scholarly journals Simulation of a large size inductively coupled plasma generator and comparison with experimental data

AIP Advances ◽  
2018 ◽  
Vol 8 (1) ◽  
pp. 015003 ◽  
2010 ◽  
Vol 208 ◽  
pp. 012056 ◽  
Author(s):  
Rakesh Kumar Dewangan ◽  
Sangeeta B Punjabi ◽  
N K Joshi ◽  
D N Barve ◽  
H A Mangalvedekar ◽  
...  

2019 ◽  
Vol 85 (1II)) ◽  
pp. 82-85 ◽  
Author(s):  
O. V. Pelipasov ◽  
R. A. Lokhtin ◽  
V. A. Labusov ◽  
N. G. Pelevina

It has been shown that «Grand» spectrometers based on a hybrid assembly of BLPP-2000 photodetector arrays produced by «VMK-Optoélektronika» can be used for atomic emission spectral analysis of solutions using inductively coupled plasma atomic emission spectroscopy (ICP-AES). For the prototype of a «Grand-ICP» spectrometer consisting of «Grand» spectrometer, microwave plasma generator, and RF (radiofrequency) generator, the following analytical characteristics were determined: element detection limit, long-term stability, linear ranges of calibration graphs for several elements, and optimal operating parameters of the microwave generator. The linear concentration range of analyte elements is 105when using a single analytical line of the element. The long-term stability is less than 2% in 6 h without using an internal standard. The detection limits are comparable to those of modern ICP spectrometers with an axial plasma survey and lie in a range of sub-microgram per liter. It has been found that the effect of superposition of the spectral lines of the plasma background, for example, OH molecular lines or others, on the analyte lines can be eliminated by subtracting the blank sample spectrum from the analyte spectrum using Atom software. The analytical characteristics of the spectrometer allow the use of the device both for developing new ICP- based systems and restoring the performance of defective ICP spectrometers.


Author(s):  
Makoto MATSUI ◽  
Suisei YAMAGISHI ◽  
Kimiya KOMURASAKI ◽  
Yoshiki YAMAGIWA ◽  
Yoshihiro ARAKAWA

Energies ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2626
Author(s):  
Usman Shoukat ◽  
Hanna Katariina Knuutila

In this study, the thermal stability and corrosivity of various CO2-loaded tertiary amine blends in both aqueous and non-aqueous form in stainless steel cylinders were studied for combined acid gas and water removal. The thermal stability was measured from the remaining amine concentration and the corrosivity was measured from the amount of various metals in blends using titration and inductively coupled plasma mass spectrometry (ICP-MS), respectively. The experimental data were used to calculate the rate constants of amine group loss. The developed model represented the experimental data very well. Solvent change from H2O to triethylene glycol (TEG) in blends decreased the thermal stability and vice versa for corrosivity. The amine stability was increased when contact with stainless steel was reduced. An increase in the amine concentration or CO2 loading at constant temperature decreased the thermal stability and vice versa for corrosivity.


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