Effect of different concentrations of sodium dodecyl sulfate and additional anionic surfactant on properties of low protein natural rubber latex

2017 ◽  
Author(s):  
Nurulhuda Abdullah ◽  
Siti Nor Qamarina Manaf ◽  
Aziana Abu Hassan
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Natural Rubber ◽  
Anionic Surfactant ◽  
Sodium Dodecyl ◽  
Natural Rubber Latex ◽  
Rubber Latex ◽  
Low Protein ◽  
Dodecyl Sulfate

Surfactant Treatment and Leaching Combination Process for Preparation of Deproteinized Natural Rubber Latex

2015 ◽  
Vol 659 ◽  
pp. 500-504
Author(s):  
Jirapornchai Suksaeree ◽  
Wirach Taweepreda ◽  
Wiwat Pichayakorn
Keyword(s):  
Natural Rubber ◽  
Skin Irritation ◽  
Sodium Dodecyl ◽  
Natural Rubber Latex ◽  
Rubber Latex ◽  
Combination Process ◽  
Surfactant Treatment ◽  
Leaching Process ◽  
Sodium Lauryl Ether Sulfate ◽  
Cocamidopropyl Betaine

This study aimed to improve the efficacy of protein removal from fresh natural rubber latex (NRL) and to decrease the production cost by using surfactant treatment and leaching combination processes. The 0.5-3% anionic surfactants, i.e. sodium dodecyl sulfate or sodium lauryl ether sulfate, nonionic tween80 surfactant, or an amphoteric cocamidopropyl betaine surfactant was used in surfactant treatment process. Moreover, water, aqueous surfactant solutions, and/or 1-5% organic solvents (i.e. ethanol, isopropanol and/or acetone) was then used in leaching process. The fresh NRL was preserved by paraben compounds in the presence of surfactant at ambient temperature for 20-120 minutes, and then centrifuged. This might prevent the skin irritation of deproteinized NRL (DNRL) caused by ammonium stabilizer that normally uses in latex industry. The upper rubber mass was then leached for upto three cycles with leaching solvents, and then finally redispersed in distilled water. The milky-like DNRLs were obtained by these processes. Their dry rubber contents were 41-47% that could be adjusted. Their viscosities were 9-13 centipoises with the pH of 6.04-6.61. The protein residues in these DNRLs were 0.0000-0.3244% which were lower than that of fresh NRL (1.2428%). These indicated the efficacy of studied deproteinization process for 73.90-100.0%. Types and concentrations of surfactant, incubation times, leaching solvents, and cycles of leaching process affected the efficacy of deproteinization process. Moreover, the properties of these dried films were not different from that of fresh NR film. This DNRL could be further used for several applications including medical skin products.

scholarly journals Preparation of low-protein natural rubber latex: Effect of polyethylene glycol

2009 ◽  
Vol 114 (2) ◽  
pp. 806-810 ◽  
Author(s):  
G. Abhilash ◽  
S. Sabharwal ◽  
Abhinav Dubey ◽  
Jose Paul ◽  
Honey John ◽  
...  
Keyword(s):  
Polyethylene Glycol ◽  
Natural Rubber ◽  
Natural Rubber Latex ◽  
Rubber Latex ◽  
Low Protein

scholarly journals Chitosan/Sodium Dodecyl Sulfate Complexes for Microencapsulation of Vitamin E and Its Release Profile—Understanding the Effect of Anionic Surfactant

2021 ◽  
Vol 15 (1) ◽  
pp. 54
Author(s):  
Jelena Milinković Budinčić ◽  
Lidija Petrović ◽  
Ljiljana Đekić ◽  
Milijana Aleksić ◽  
Jadranka Fraj ◽  
...  
Keyword(s):  
Vitamin E ◽  
Sodium Dodecyl Sulfate ◽  
Anionic Surfactant ◽  
Sodium Dodecyl ◽  
Pharmaceutical Products ◽  
Release Mechanism ◽  
Bioactive Substances ◽  
Water Emulsion ◽  
Dodecyl Sulfate

Microencapsulation of bioactive substances is a common strategy for their protection and release rate control. The use of chitosan (Ch) is particularly promising due to its abundance, biocompatibility, and interaction with anionic surfactants to form complexes of different characteristics with relevance for use in microcapsule wall design. In this study, Ch/sodium dodecyl sulfate (SDS) microcapsules, without and with cross-linking agent (formaldehyde (FA) or glutaraldehyde (GA)), were obtained by the spray drying of vitamin E loaded oil-in-water emulsion. All of the microcapsules had good stability during the drying process. Depending on the composition, their product yield, moisture content, and encapsulation efficiency varied between 11–34%, 1.14–1.62%, and 94–126%, respectively. SEM and FTIR analysis results indicate that SDS as well as cross-linkers significantly affected the microcapsule wall properties. The profiles of in vitro vitamin E release from the investigated microcapsules fit with the Korsmeyer-Peppas model (r2 > 0.9). The chemical structure of the anionic surfactant was found to have a significant effect on the vitamin E release mechanism. Ch/SDS coacervates may build a microcapsule wall without toxic crosslinkers. This enabled the combined diffusion/swelling based release mechanism of the encapsulated lipophilic substance, which can be considered favorable for utilization in food and pharmaceutical products.

scholarly journals Study of Elodea canadensis elimination of Sodium Dodecyl Sulphate and NH4Cl

2021 ◽  
Vol 866 (1) ◽  
pp. 012025
Author(s):  
S E Sergienko ◽  
S S Timofeeva ◽  
A B Kupchinsky ◽  
G Chaneva ◽  
D I Stom ◽  
...  
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Anionic Surfactant ◽  
Sodium Dodecyl Sulphate ◽  
Sodium Dodecyl ◽  
Ammonium Nitrogen ◽  
Elodea Canadensis ◽  
Initial Value ◽  
Dodecyl Sulfate ◽  
Negative Effect ◽  
Wet Weight

Abstract The absorption of an anionic surfactant - sodium dodecyl sulfate (SDS) by a Elodea canadensis was studied. Macrophyte (20 g/L wet weight) reduced the concentration of this surfactant from 2 mg/L by 90% within 2 days. A negative effect of SDS on the elimination of ammonium nitrogen by E. canadensis was shown with its content from 1·10-4 M. Thus, in the presence of 1·10-4 M SDS, E. canadensis reduced the concentration of ammonium nitrogen by 51% of the initial value in 2 days (in the control - without surfactants - 92% of the pollutant was absorbed).

Mixing Behavior of Cationic Hydrotropes with Anionic Surfactant Sodium Dodecyl Sulfate

2011 ◽  
Vol 32 (10) ◽  
pp. 1452-1458 ◽  
Author(s):  
Ziya Ahmad Khan ◽  
Mohammad Kamil ◽  
Othman Sulaiman ◽  
Rokiah Hashim ◽  
M. N. Mohamad Ibrahim ◽  
...  
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Anionic Surfactant ◽  
Sodium Dodecyl ◽  
Mixing Behavior ◽  
Dodecyl Sulfate

REMOVING EXTRACTABLE PROTEINS IN NATURAL RUBBER LATEX BY CALCIUM CHLORIDE FROM CHICKEN EGGSHELLS

2011 ◽  
Vol 84 (4) ◽  
pp. 543-564 ◽  
Author(s):  
Nuchnapa Tangboriboon ◽  
Prapapan Phudkrachang ◽  
Ruksapong Kunanuruksapong ◽  
Anuvat Sirivat
Keyword(s):  
Natural Rubber ◽  
Calcium Chloride ◽  
Electrostatic Interactions ◽  
Sodium Dodecyl ◽  
Natural Rubber Latex ◽  
Film Surface ◽  
Latex Film ◽  
Rubber Latex ◽  
Skin Contact ◽  
Extractable Protein

Abstract Controlling the level of the extractable protein contents in a natural rubber latex is important to the sensitization of natural rubber latex products users. Allergies caused by latex products cause a serious problem in which the sweat removes proteins and allowing a skin contact causing allergic reactions. Calcium oxide from calcined chicken eggshells at 900 °C for 1 h was dissolved in 2M HCl (CaCl2) and used as the thickening agent in which it can modify the protein structure. The eggshells were characterized by the particle size analysis, the impedance analysis, simultaneous thermal analysis (STA), x-ray diffraction (XRD), and Fourier transform infrared spectra (FTIR). Calcium chloride (CaCl2) interacts with the protein molecules and the solvent ions through the hydrogen bonding and the electrostatic interactions driving the extractable protein toward the film surface. Sodium dodecyl sulphate was used as the stabilizer in the natural rubber latex film formation. The extractable protein contents were measured and determined by the modified Lowry method. The concentrated latex samples were further characterized by FTIR, scanning electron microscope, and XRD and the results were reported here. Moreover, near infrared was used to measure the extractable protein spectra of the concentrated latex compounds in the region of 1100–2500 nm.

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