Investigating phase separation and structural coloration of self-assembled ternary polymer thin films

2016 ◽  
Vol 109 (10) ◽  
pp. 103702 ◽  
Author(s):  
Varun Vohra ◽  
Francesco Galeotti ◽  
Umberto Giovanella ◽  
Takuya Anzai ◽  
Erika Kozma ◽  
...  
2008 ◽  
Vol 112 (22) ◽  
pp. 8184-8191 ◽  
Author(s):  
Ryodai Kanemoto ◽  
Abdulaziz Anas ◽  
Yusuke Matsumoto ◽  
Rintaro Ueji ◽  
Tamitake Itoh ◽  
...  

2003 ◽  
Vol 15 (14) ◽  
pp. 2699-2701 ◽  
Author(s):  
Ziqi Liang ◽  
Mindaugas Rackaitis ◽  
Kun Li ◽  
Evangelos Manias ◽  
Qing Wang

2015 ◽  
Vol 28 (4) ◽  
pp. 640-648 ◽  
Author(s):  
Karthik Krishnan ◽  
Tohru Tsuruoka ◽  
Cedric Mannequin ◽  
Masakazu Aono

2013 ◽  
Vol 46 (6) ◽  
pp. 1610-1615 ◽  
Author(s):  
Hiroki Ogawa ◽  
Tsukasa Miyazaki ◽  
Keisuke Shimokita ◽  
Akihiko Fujiwara ◽  
Mikihito Takenaka ◽  
...  

A high-precision spin-coater system has been developed for the investigation of formation mechanisms of self-assembled structures in polymer thin films. The spin coater was designed to have small axial deflection (<2.6 µm at the maximum speed of 2000 r min−1) during rotation in order to maintain the relative position with respect to the incident X-ray beam, and to be compact (70 mm) in height to facilitate incorporation into anin situsynchrotron radiation grazing-incidence small-angle X-ray scattering (GISAXS) system. The first results of simultaneous measurements on the morphology and film thickness of a triblock copolymer with time resolution of 64 ms during thin-film formation at 2000 r min−1provide indispensable information for understanding the vertically grown lamellar structure on the film surface.


2000 ◽  
Vol 661 ◽  
Author(s):  
Y. Jiang ◽  
A. Saxena ◽  
T. Lookman ◽  
J. F. Douglas

ABSTRACTMotivated by recent experiments on filled polymer thin films, we study the effect of the presence of filler particles on phase separating mixtures. Using a generalized Cahn-Hillard-cook model, we show that the preferential wetting of one phase on the filler surface generates transient composition waves in the phase separating blends. The interference of the composition waves from different particles can stabilize the transient patterns, leading to desirable control of the morphology.


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