Unraveling the energy dependence in large ΔE (V→RT) energy transfer: Separation of ΔE and probability in the collisional relaxation of highly vibrationally excited pyrazine (Evib=36 000 to 41 000 cm−1) by CO2

1999 ◽  
Vol 111 (16) ◽  
pp. 7373-7382 ◽  
Author(s):  
Mark C. Wall ◽  
Andrew E. Lemoff ◽  
Amy S. Mullin
Keyword(s):  
Energy Transfer ◽  
Energy Dependence ◽  
Collisional Relaxation ◽  
Vibrationally Excited

Energy transfer of highly vibrationally excited naphthalene. I. Translational collision energy dependence

2007 ◽  
Vol 127 (10) ◽  
pp. 104311 ◽  
Author(s):  
Chen-Lin Liu ◽  
Hsu Chen Hsu ◽  
Yuan Chin Hsu ◽  
Chi-Kung Ni
Keyword(s):  
Energy Transfer ◽  
Energy Dependence ◽  
Collision Energy ◽  
Vibrationally Excited

scholarly journals The calculation of TV, VT, VV, VV' − rate coefficients for the collisions of the main atmospheric components

1998 ◽  
Vol 16 (7) ◽  
pp. 838-846 ◽  
Author(s):  
A. S. Kirillov
Keyword(s):  
Experimental Data ◽  
Energy Transfer ◽  
Vibrational Energy ◽  
Relaxation Times ◽  
Atmospheric Composition ◽  
Rate Coefficients ◽  
Frequency Change ◽  
Vibrational Energy Transfer ◽  
Ion Chemistry ◽  
Vibrationally Excited

Abstract. The first-order perturbation approximation is applied to calculate the rate coefficients of vibrational energy transfer in collisions involving vibrationally excited molecules in the absence of non-adiabatic transitions. The factors of molecular attraction, oscillator frequency change, anharmonicity, 3-dimensionality and quasiclassical motion have been taken into account in the approximation. The analytical expressions presented have been normalized on experimental data of VT-relaxation times in N2 and O2 to obtain the steric factors and the extent of repulsive exchange potentials in collisions N2-N2 and O2-O2. The approach was applied to calculate the rate coefficients of vibrational-vibrational energy transfer in the collisions N2-N2, O2-O2 and N2-O2. It is shown that there is good agreement between our calculations and experimental data for all cases of energy transfer considered.Key words. Ionosphere (Auroral ionosphere; ion chemistry and composition). Atmospheric composition and structure (Aciglow and aurora).

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