Electron spin resonance and theoretical studies of the 14N⋅⋅⋅⋅14N and 15N⋅⋅⋅⋅15N spin-pair radicals in neon matrices: The effects of mixing among the 1Σg+, 3Σu+, 5Σg+, and 7Σu+ electronic states

1999 ◽  
Vol 111 (7) ◽  
pp. 3145-3154 ◽  
Author(s):  
Lon B. Knight ◽  
Benjamin A. Bell ◽  
Daryl P. Cobranchi ◽  
Ernest R. Davidson
2011 ◽  
Vol 170 ◽  
pp. 170-173 ◽  
Author(s):  
Vladimir A. Ivanshin ◽  
T.O. Litvinova ◽  
A.A. Sukhanov ◽  
N.A. Ivanshin ◽  
B. Endeward

We review electron spin resonance (ESR) experiments in several concentrated Yb-, Ce-, and Eu-based intermetallic systems. Recent theoretical studies attribute well resolved ESR signals with hybridization effects between 4f and conduction electrons (CE) in the presence of ferromagnetic (FM) fluctuations. We believe that the ESR absorption is caused here by a novel type of ESR excitations – hybridized electronic states, which are created in some strongly correlated electronic systems due to hybridization between the 4f-orbitals and the wavefunctions of the CE of the outer d, s, and p shells in conjunction with FM RKKY interaction.


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