Vibration-rotation emission spectra and combined isotopomer analyses for the coinage metal hydrides: CuH & CuD, AgH & AgD, and AuH & AuD

1999 ◽  
Vol 110 (24) ◽  
pp. 11756-11767 ◽  
Author(s):  
Jenning Y. Seto ◽  
Zulfikar Morbi ◽  
Frank Charron ◽  
Sang K. Lee ◽  
Peter F. Bernath ◽  
...  
Keyword(s):  
Metal Hydrides ◽  
Emission Spectra ◽  
Coinage Metal ◽  
Vibration Rotation

scholarly journals Reactivity of Coinage Metal Hydrides for the Production of H 2 Molecules

ChemistryOpen ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 722-723
Author(s):  
Iñigo Iribarren ◽  
Goar Sánchez‐Sanz ◽  
José Elguero ◽  
Ibon Alkorta ◽  
Cristina Trujillo
Keyword(s):  
Metal Hydrides ◽  
Coinage Metal

Vibration-rotation pattern in acetylene. II. Introduction of Coriolis coupling in the global model and analysis of emission spectra of hot acetylene around 3 μm

2009 ◽  
Vol 131 (11) ◽  
pp. 114301 ◽  
Author(s):  
Badr Amyay ◽  
Séverine Robert ◽  
Michel Herman ◽  
André Fayt ◽  
Balakrishna Raghavendra ◽  
...  
Keyword(s):  
Emission Spectra ◽  
Global Model ◽  
Coriolis Coupling ◽  
Rotation Pattern ◽  
Vibration Rotation

Vibrational corrections to electric properties of relativistic molecules: The coinage metal hydrides

2001 ◽  
Vol 114 (1) ◽  
pp. 198 ◽  
Author(s):  
Aggelos Avramopoulos ◽  
Victoria E. Ingamells ◽  
Manthos G. Papadopoulos ◽  
Andrzej J. Sadlej
Keyword(s):  
Metal Hydrides ◽  
Electric Properties ◽  
Coinage Metal

Vibration−Rotation Emission Spectra of Gaseous ZnH2and ZnD2

2004 ◽  
Vol 126 (44) ◽  
pp. 14356-14357 ◽  
Author(s):  
Alireza Shayesteh ◽  
Dominique R. T. Appadoo ◽  
Iouli E. Gordon ◽  
Peter F. Bernath
Keyword(s):  
Emission Spectra ◽  
Vibration Rotation

scholarly journals Reactivity of Coinage Metal Hydrides for the Production of H 2 Molecules

ChemistryOpen ◽  
2021 ◽  
Author(s):  
Iñigo Iribarren ◽  
Goar Sánchez‐Sanz ◽  
José Elguero ◽  
Ibon Alkorta ◽  
Cristina Trujillo
Keyword(s):  
Metal Hydrides ◽  
Coinage Metal

scholarly journals Synthesis and Structural Characterization of a Silver(I) Pyrazolato Coordination Polymer

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1015
Author(s):  
Kiyoshi Fujisawa ◽  
Takuya Nemoto ◽  
Yui Morishima ◽  
Daniel B. Leznoff
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Emission Spectra ◽  
Supramolecular Assembly ◽  
Luminescent Properties ◽  
Spectroscopic Properties ◽  
Coinage Metal ◽  
Argentophilic Interactions ◽  
Linear Coordination

Coinage metal(I)···metal(I) interactions are widely of interest in fields such as supramolecular assembly and unique luminescent properties, etc. Only two types of polynuclear silver(I) pyrazolato complexes have been reported, however, and no detailed spectroscopic characterizations have been reported. An unexpected synthetic method yielded a polynuclear silver(I) complex [Ag(μ-L1Clpz)]n (L1Clpz− = 4-chloride-3,5-diisopropyl-1-pyrazolate anion) by the reaction of {[Ag(μ-L1Clpz)]3}2 with (nBu4N)[Ag(CN)2]. The obtained structure was compared with the known hexanuclear silver(I) complex {[Ag(μ-L1Clpz)]3}2. The Ag···Ag distances in [Ag(μ-L1Clpz)]n are slightly shorter than twice Bondi’s van der Waals radius, indicating some Ag···Ag argentophilic interactions. Two Ag–N distances in [Ag(μ-L1Clpz)]n were found: 2.0760(13) and 2.0716(13) Å, and their N–Ag–N bond angles of 180.00(7)° and 179.83(5)° indicate that each silver(I) ion is coordinated by two pyrazolyl nitrogen atoms with an almost linear coordination. Every five pyrazoles point in the same direction to form a 1-D zig-zag structure. Some spectroscopic properties of [Ag(μ-L1Clpz)]n in the solid-state are different from those of {[Ag(μ-L1Clpz)]3}2 (especially in the absorption and emission spectra), presumably attributable to this zig-zag structure having longer but differently arranged intramolecular Ag···Ag interactions of 3.39171(17) Å. This result clearly demonstrates the different physicochemical properties in the solid-state between 1-D coordination polymer and metalacyclic trinuclear (hexanuclear) or tetranuclear silver(I) pyrazolate complexes.

Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity

2016 ◽  
Vol 116 (15) ◽  
pp. 8318-8372 ◽  
Author(s):  
Abraham J. Jordan ◽  
Gojko Lalic ◽  
Joseph P. Sadighi
Keyword(s):  
Metal Hydrides ◽  
Coinage Metal

The vibration-rotation emission spectra of gaseous CdH2 and CdD2

2005 ◽  
Vol 122 (19) ◽  
pp. 194301 ◽  
Author(s):  
Shanshan Yu ◽  
Alireza Shayesteh ◽  
Peter F. Bernath
Keyword(s):  
Emission Spectra ◽  
Vibration Rotation
Sign in / Sign up

Export Citation Format

Share Document