Vibration−Rotation Emission Spectra of Gaseous ZnH2and ZnD2

2004 ◽  
Vol 126 (44) ◽  
pp. 14356-14357 ◽  
Author(s):  
Alireza Shayesteh ◽  
Dominique R. T. Appadoo ◽  
Iouli E. Gordon ◽  
Peter F. Bernath
2009 ◽  
Vol 131 (11) ◽  
pp. 114301 ◽  
Author(s):  
Badr Amyay ◽  
Séverine Robert ◽  
Michel Herman ◽  
André Fayt ◽  
Balakrishna Raghavendra ◽  
...  

1999 ◽  
Vol 110 (24) ◽  
pp. 11756-11767 ◽  
Author(s):  
Jenning Y. Seto ◽  
Zulfikar Morbi ◽  
Frank Charron ◽  
Sang K. Lee ◽  
Peter F. Bernath ◽  
...  

2005 ◽  
Vol 122 (19) ◽  
pp. 194301 ◽  
Author(s):  
Shanshan Yu ◽  
Alireza Shayesteh ◽  
Peter F. Bernath

Vibration-rotation transitions of CO(X 1 Ʃ + ) have been observed as infrared chemiluminescence from the reactions of O( 3 P) with C 2 H 2 , C 3 O 2 and HC 3 N. The emission spectra, observed from a spherical flow reactor at low pressures (0.1 to 2 Torr) were characteristic for each reaction system, and in some cases depended on the relative flow rates of the reactants and were affected by the addition of atomic hydrogen. These changes in spectral distribution can yield valuable information about the mechanisms of the elementary reactions involved. Thus in the O + C 2 H 2 reaction, the distribution extending to v ' = 14 which predominates at low fuel flows is associated with the reactions O + C 2 H 2 = CO + CH 2 + 48 kcal/mol (200 kJ/mol), O + CH 2 =CO + 2H + 73 kcal/mol (306 kJ/mol). An additional distribution extending up to v ' = 33 (163 kcal/mol, 680 kJ/mol) is observed at high acetylene flows and in the presence of added hydrogen. This is attributed to the reaction O + CH = CO + H + 176 kcal/mol (736 kJ/mol). Similar emission is also observed from the O + C 3 O 2 reaction when atomic hydrogen is added; in its absence, the dominant CO emission comes from levels v ≼ 8 and is attributed to the reaction O + C 3 O 2 = 3CO+115 kcal/mol (480 kJ/mol).


Author(s):  
Y. Y. Wang ◽  
H. Zhang ◽  
V. P. Dravid ◽  
H. Zhang ◽  
L. D. Marks ◽  
...  

Azuma et al. observed planar defects in a high pressure synthesized infinitelayer compound (i.e. ACuO2 (A=cation)), which exhibits superconductivity at ~110 K. It was proposed that the defects are cation deficient and that the superconductivity in this material is related to the planar defects. In this report, we present quantitative analysis of the planar defects utilizing nanometer probe xray microanalysis, high resolution electron microscopy, and image simulation to determine the chemical composition and atomic structure of the planar defects. We propose an atomic structure model for the planar defects.Infinite-layer samples with the nominal chemical formula, (Sr1-xCax)yCuO2 (x=0.3; y=0.9,1.0,1.1), were prepared using solid state synthesized low pressure forms of (Sr1-xCax)CuO2 with additions of CuO or (Sr1-xCax)2CuO3, followed by a high pressure treatment.Quantitative x-ray microanalysis, with a 1 nm probe, was performed using a cold field emission gun TEM (Hitachi HF-2000) equipped with an Oxford Pentafet thin-window x-ray detector. The probe was positioned on the planar defects, which has a 0.74 nm width, and x-ray emission spectra from the defects were compared with those obtained from vicinity regions.


1965 ◽  
Vol 62 ◽  
pp. 600-603 ◽  
Author(s):  
Armand Lévy ◽  
Inga Rossi ◽  
Colette Joffrin ◽  
Nguyen Van Thanh
Keyword(s):  

1997 ◽  
Vol 7 (C2) ◽  
pp. C2-515-C2-516
Author(s):  
H. Agren ◽  
L. G.M. Pettersson ◽  
V. Carravetta ◽  
Y. Luo ◽  
L. Yang ◽  
...  

1980 ◽  
Vol 41 (12) ◽  
pp. 1431-1436 ◽  
Author(s):  
M. Larzillière ◽  
F. Launay ◽  
J.-Y. Roncin

1979 ◽  
Vol 40 (C2) ◽  
pp. C2-417-C2-419
Author(s):  
C. H.W. Jones ◽  
M. Dombsky
Keyword(s):  

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