Fluorescence excitation spectroscopy of the Ar–HCO(X̃ 2A′,B̃ 2A′) van der Waals complex

1997 ◽  
Vol 107 (3) ◽  
pp. 680-690 ◽  
Author(s):  
Scott A. Wright ◽  
Paul J. Dagdigian
1990 ◽  
Vol 92 (5) ◽  
pp. 2828-2836 ◽  
Author(s):  
C. Dedonder‐Lardeux ◽  
C. Jouvet ◽  
M. Richard‐Viard ◽  
D. Solgadi

1991 ◽  
Vol 94 (3) ◽  
pp. 1759-1764 ◽  
Author(s):  
C. Jouvet ◽  
C. Lardeux‐Dedonder ◽  
S. Martrenchard ◽  
D. Solgadi

1984 ◽  
Vol 62 (12) ◽  
pp. 1293-1299 ◽  
Author(s):  
W. Leo Meerts ◽  
W. A. Majewski ◽  
W. M. van Herpen

The high-resolution fluorescence excitation spectrum of the fluorene molecule and its van der Waals complex with argon has been studied. Rotationally resolved spectra were obtained by combining a well-collimated supersonic molecular beam with a single frequency tunable ultraviolet (uv) source. The S1 ← S0[Formula: see text] vibronic transitions in fluorene and fluorine–argon were observed. The rotational constants of both molecules were determined and from these the structure of the fluorine–argon complex has been deduced. The argon atom is located above the middle five-membered ring. The coordinates of the position vector of the argon atom in the complex in the centre-of-mass system of fluorene are r = (3.46 ± 0.03) Å and [Formula: see text]. A model calculation of the fluorine–Ar structure was found to be in quite good agreement with the experimental result. The newly introduced inertial defect of the complex ΔIc = −7(3) amu Å2 provided an experimental measure of the zero-point motion of argon in the complex.


1978 ◽  
Vol 68 (10) ◽  
pp. 4477-4480 ◽  
Author(s):  
Glenn Kubiak ◽  
Pamela S. H. Fitch ◽  
Lennard Wharton ◽  
Donald H. Levy

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