Direct, spectroscopic measurement of the rotational state distribution of HCl fragments from the vibrational predissociation of ν2=1 (HCl)2produced by stimulated Raman excitation

1994 ◽  
Vol 100 (3) ◽  
pp. 2385-2387 ◽  
Author(s):  
Joseph Serafin ◽  
Hong Ni ◽  
James J. Valentini
Keyword(s):  
Spectroscopic Measurement ◽  
Rotational State ◽  
State Distribution ◽  
Vibrational Predissociation ◽  
Stimulated Raman

scholarly journals Origin of the “odd” behavior in the ultraviolet photochemistry of ozone

2020 ◽  
Vol 117 (35) ◽  
pp. 21065-21069
Author(s):  
Shanyu Han ◽  
Carolyn E. Gunthardt ◽  
Richard Dawes ◽  
Daiqian Xie ◽  
Simon W. North ◽  
...  
Keyword(s):  
Quantum Theory ◽  
Selection Rule ◽  
Rotational Quantum Number ◽  
Rotational State ◽  
Isotopic Enrichment ◽  
State Distribution ◽  
Rotational States ◽  
Increasing Temperature ◽  
Full Quantum ◽  
Curve Crossing

The origin of the even–odd rotational state population alternation in the16O2(a1Δg) fragments resulting from the ultraviolet (UV) photodissociation of16O3, a phenomenon first observed over 30 years ago, has been elucidated using full quantum theory. The calculated16O2(a1Δg) rotational state distribution following the 266-nm photolysis of 60 K ozone shows a strong even–odd propensity, in excellent agreement with the new experimental rotational state distribution measured under the same conditions. Theory indicates that the even rotational states are significantly more populated than the adjacent odd rotational states because of a preference for the formation of the A′ Λ-doublet, which can only occupy even rotational states due to the exchange symmetry of the two bosonic16O nuclei, and thus not as a result of parity-selective curve crossing as previously proposed. For nonrotating ozone, its dissociation on the excited B1A′ state dictates that only A′ Λ-doublets are populated, due to symmetry conservation. This selection rule is relaxed for rotating parent molecules, but a preference still persists for A′ Λ-doublets. The A′′/A′ ratio increases with increasing ozone rotational quantum number, and thus with increasing temperature, explaining the previously observed temperature dependence of the even–odd population alternation. In light of these results, it is concluded that the previously proposed parity-selective curve-crossing mechanism cannot be a source of heavy isotopic enrichment in the atmosphere.

Chemical Reactions in Clusters

1996 ◽  
Keyword(s):  
State Of The Art ◽  
Transfer Reactions ◽  
Art Theory ◽  
State Distribution ◽  
Cluster Chemistry ◽  
New Developments ◽  
Vibrational Predissociation ◽  
Current State ◽  
Proton Transfer Reactions ◽  
Dynamical Information

This book covers important new developments of the last five years in the area of cluster chemistry, presenting an excellent view of the successes and shortcomings of both current state-of-the-art theory and experiment. Each chapter, contributed by a leading expert, places heavy emphasis on theory without which the detailed analysis of the spectroscopic and kinetic results would be compromised. The cluster reactions reviewed in this work include electron and proton transfer reactions, hot atom reactions, vibrational predissociation, radical reactions, and ionic reactions. Some of the theories applied throughout the text are product state distribution determinations, state-to-state dynamical information, and access to the transition stage of the reaction. The discussions serve as a benchmark of how far the field has come since the mid 1980's and will be a good update for students and researchers interested in this area of physical chemistry.

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