CH+H2 reaction kinetics: Temperature and pressure dependence and Rice–Ramsperger–Kassel–Marcus‐master‐equation calculation

1993 ◽  
Vol 99 (5) ◽  
pp. 3597-3603 ◽  
Author(s):  
Andrew McIlroy ◽  
Frank P. Tully
Keyword(s):  
Master Equation ◽  
Reaction Kinetics ◽  
Pressure Dependence ◽  
Temperature And Pressure

Determination of the temperature and pressure dependence of the reaction OH + C2H4from 200–400 K using experimental and master equation analyses

2006 ◽  
Vol 8 (48) ◽  
pp. 5633-5642 ◽  
Author(s):  
Patricia A. Cleary ◽  
Maria Teresa Baeza Romero ◽  
Mark A. Blitz ◽  
Dwayne E. Heard ◽  
Michael J. Pilling ◽  
...  
Keyword(s):  
Master Equation ◽  
Pressure Dependence ◽  
Temperature And Pressure

Measurements of real non-Newtonian response for liquid lubricants under moderate pressures

2001 ◽  
Vol 215 (3) ◽  
pp. 223-233 ◽  
Author(s):  
S Bair
Keyword(s):  
Numerical Simulation ◽  
Kinetic Theory ◽  
Simple Shear ◽  
Pressure Dependence ◽  
Shear Stresses ◽  
Current Interest ◽  
Flow Properties ◽  
Power Law Fluid ◽  
Temperature And Pressure

A thorough characterization of all viscous flow properties relevant to steady simple shear was carried out for five liquid lubricants of current interest to tribology. Shear stresses were generated to values significant to concentrated contact lubrication. Two types of non-Newtonian response were observed: shear-thinning as a power-law fluid and near rate-independence. Functions and parameters were obtained for the temperature and pressure dependence of the viscosity and of the time constant for the Carreau-Yasuda equation. Results are consistent with free volume and kinetic theory, but directly contradict many assumptions currently utilized for numerical simulation and for extracting rheological properties from contact measurements.

Measured temperature and pressure dependence of Vp and Vs in compacted, polycrystalline sI methane and sII methane–ethane hydrate

2003 ◽  
Vol 81 (1-2) ◽  
pp. 47-53 ◽  
Author(s):  
M B Helgerud ◽  
W F Waite ◽  
S H Kirby ◽  
A Nur
Keyword(s):  
High Pressure ◽  
Shear Wave ◽  
Pressure Dependence ◽  
Gas Hydrate ◽  
Pressure Vessel ◽  
Wave Speed ◽  
Measured Temperature ◽  
Shear Wave Speed ◽  
Temperature And Pressure ◽  
Fixed End

We report on compressional- and shear-wave-speed measurements made on compacted polycrystalline sI methane and sII methane–ethane hydrate. The gas hydrate samples are synthesized directly in the measurement apparatus by warming granulated ice to 17°C in the presence of a clathrate-forming gas at high pressure (methane for sI, 90.2% methane, 9.8% ethane for sII). Porosity is eliminated after hydrate synthesis by compacting the sample in the synthesis pressure vessel between a hydraulic ram and a fixed end-plug, both containing shear-wave transducers. Wave-speed measurements are made between –20 and 15°C and 0 to 105 MPa applied piston pressure. PACS No.: 61.60Lj

Sign in / Sign up

Export Citation Format

Share Document