The Stark effect in methane’s 3ν1+ν3 vibrational overtone band

1993 ◽  
Vol 99 (2) ◽  
pp. 1429-1432 ◽  
Author(s):  
Kirk Boraas ◽  
David F. De Boer ◽  
Zhen Lin ◽  
James P. Reilly
Keyword(s):  
Stark Effect ◽  
Overtone Band ◽  
Vibrational Overtone

scholarly journals Application of the Spectral Structure Parameterization technique: retrieval of total water vapor columns from GOME

2003 ◽  
Vol 3 (1) ◽  
pp. 145-160 ◽  
Author(s):  
R. Lang ◽  
J. E. Williams ◽  
W. J. van der Zande ◽  
A. N. Maurellis
Keyword(s):  
Water Vapor ◽  
Scattered Light ◽  
Sampling Technique ◽  
Optical Absorption Coefficient ◽  
Spectral Structure ◽  
Total Water ◽  
Transfer Scheme ◽  
Overtone Band ◽  
Vibrational Overtone ◽  
Reflectivity Spectra

Abstract. We use a recently proposed spectral sampling technique for measurements of atmospheric transmissions called the Spectral Structure Parameterization (SSP) in order to retrieve total water vapor columns (WVC) from reflectivity spectra measured by the Global Ozone Monitoring Experiment (GOME). SSP provides a good compromise between efficiency and speed when performing retrievals on highly structured spectra of narrow-band absorbers like water vapor. We show that SSP can be implemented in a radiative transfer scheme which treats both direct-path absorption and absorption by singly-scattered light directly. For the retrieval we exploit a ro-vibrational overtone band of water vapor located in the visible around 590 nm. We compare our results to independent values given by the data assimilation model of ECMWF. In addition, results are compared to those obtained from the more accurate, but more computationally expensive, Optical Absorption Coefficient Spectroscopy (OACS).

A study of molecular rotation in dense fluids from the first vibrational overtone band shape of HCl in Xe fluid

2004 ◽  
Vol 6 (4) ◽  
pp. 725-729 ◽  
Author(s):  
Justo Pérez ◽  
Antonio Padilla ◽  
Michael O. Bulanin ◽  
Alexandra V. Domanskaya ◽  
Klaus Kerl
Keyword(s):  
Molecular Rotation ◽  
Band Shape ◽  
Dense Fluids ◽  
Overtone Band ◽  
Vibrational Overtone

Observation of the Stark effect in high-overtone band transitions of NH_3

1989 ◽  
Vol 14 (10) ◽  
pp. 488 ◽  
Author(s):  
Ken’ichi Nakagawa ◽  
Yoshiki Moriwaki ◽  
Tadao Shimizu
Keyword(s):  
Stark Effect ◽  
Overtone Band ◽  
High Overtone

High resolution study of methane’s 3ν1+ν3 vibrational overtone band

1994 ◽  
Vol 100 (11) ◽  
pp. 7916-7927 ◽  
Author(s):  
Kirk Boraas ◽  
Zhen Lin ◽  
James P. Reilly
Keyword(s):  
High Resolution ◽  
Overtone Band ◽  
Vibrational Overtone ◽  
Resolution Study

scholarly journals Application of the Spectral Structure Parameterization technique: retrieval of total water vapor columns from GOME

2002 ◽  
Vol 2 (4) ◽  
pp. 1097-1130 ◽  
Author(s):  
R. Lang ◽  
J. E. Williams ◽  
W. J. van der Zande ◽  
A. N. Maurellis
Keyword(s):  
Water Vapor ◽  
Scattered Light ◽  
Sampling Technique ◽  
Optical Absorption Coefficient ◽  
Spectral Structure ◽  
Total Water ◽  
Transfer Scheme ◽  
Overtone Band ◽  
Vibrational Overtone ◽  
Reflectivity Spectra

Abstract. We use a recently proposed spectral sampling technique for measurements of atmospheric transmissions called the Spectral Structure Parameterization (SSP) in order to retrieve total water vapor columns (WVC) from reflectivity spectra measured by the Global Ozone Monitoring Experiment (GOME). SSP provides a good compromise between efficiency and speed when performing retrievals on highly structured spectra of narrow-band absorbers like water vapor. We show that SSP can be implemented in a radiative transfer scheme which treats both direct-path absorption and absorption by singly scattered light directly. For the retrieval we exploit a ro-vibrational overtone band of water vapor located in the visible around 590 nm. We compare our results to independent values given by the data assimilation model of ECMWF. In addition, results are compared to those obtained from the more accurate, but slower, Optical Absorption Coefficient Spectroscopy (OACS).

A TEM study of electron tunneling in biological macromolecules

1987 ◽  
Vol 45 ◽  
pp. 140-141
Author(s):  
J. A. Panitz
Keyword(s):  
Stark Effect ◽  
Electron Tunneling ◽  
Imaging Modality ◽  
Tunneling Current ◽  
Biological Species ◽  
Scanning Tunneling ◽  
Biological Macromolecules ◽  
Flat Surfaces ◽  
Virus Particles ◽  
Stm Images

Tunneling is a ubiquitous phenomenon. Alpha particle disintegration, the Stark effect, superconductivity in thin films, field-emission, and field-ionization are examples of electron tunneling phenomena. In the scanning tunneling microscope (STM) electron tunneling is used as an imaging modality. STM images of flat surfaces show structure at the atomic level. However, STM images of large biological species deposited onto flat surfaces are disappointing. For example, unstained virus particles imaged in the STM do not resemble their TEM counterparts.It is not clear how an STM image of a biological species is formed. Most biological species are large compared to the nominal electrode separation of ∼ 1nm that is required for electron tunneling. To form an image of a biological species, the tunneling electrodes must be separated by a distance that would normally be too large for a tunneling current to be observed.

A. C. Stark effect on the 4713 Å line emitted by a helium glow discharge in the field of a multimode T.E.A. CO2 laser

1982 ◽  
Vol 43 (6) ◽  
pp. 875-881 ◽  
Author(s):  
B. Dubreuil ◽  
P. Pignolet ◽  
A. Catherinot ◽  
P. Davy
Keyword(s):  
Glow Discharge ◽  
Co2 Laser ◽  
Stark Effect
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