Stark field induced perturbations in the ν[sub 2]+3ν[sub 3] vibrational overtone band of acetylene

2001 ◽  
Vol 114 (10) ◽  
pp. 4490 ◽  
Author(s):  
J. A. Barnes ◽  
T. E. Gough ◽  
M. Stoer
Keyword(s):  
Overtone Band ◽  
Vibrational Overtone ◽  
Stark Field

scholarly journals Application of the Spectral Structure Parameterization technique: retrieval of total water vapor columns from GOME

2003 ◽  
Vol 3 (1) ◽  
pp. 145-160 ◽  
Author(s):  
R. Lang ◽  
J. E. Williams ◽  
W. J. van der Zande ◽  
A. N. Maurellis
Keyword(s):  
Water Vapor ◽  
Scattered Light ◽  
Sampling Technique ◽  
Optical Absorption Coefficient ◽  
Spectral Structure ◽  
Total Water ◽  
Transfer Scheme ◽  
Overtone Band ◽  
Vibrational Overtone ◽  
Reflectivity Spectra

Abstract. We use a recently proposed spectral sampling technique for measurements of atmospheric transmissions called the Spectral Structure Parameterization (SSP) in order to retrieve total water vapor columns (WVC) from reflectivity spectra measured by the Global Ozone Monitoring Experiment (GOME). SSP provides a good compromise between efficiency and speed when performing retrievals on highly structured spectra of narrow-band absorbers like water vapor. We show that SSP can be implemented in a radiative transfer scheme which treats both direct-path absorption and absorption by singly-scattered light directly. For the retrieval we exploit a ro-vibrational overtone band of water vapor located in the visible around 590 nm. We compare our results to independent values given by the data assimilation model of ECMWF. In addition, results are compared to those obtained from the more accurate, but more computationally expensive, Optical Absorption Coefficient Spectroscopy (OACS).

A study of molecular rotation in dense fluids from the first vibrational overtone band shape of HCl in Xe fluid

2004 ◽  
Vol 6 (4) ◽  
pp. 725-729 ◽  
Author(s):  
Justo Pérez ◽  
Antonio Padilla ◽  
Michael O. Bulanin ◽  
Alexandra V. Domanskaya ◽  
Klaus Kerl
Keyword(s):  
Molecular Rotation ◽  
Band Shape ◽  
Dense Fluids ◽  
Overtone Band ◽  
Vibrational Overtone

The Stark effect in methane’s 3ν1+ν3 vibrational overtone band

1993 ◽  
Vol 99 (2) ◽  
pp. 1429-1432 ◽  
Author(s):  
Kirk Boraas ◽  
David F. De Boer ◽  
Zhen Lin ◽  
James P. Reilly
Keyword(s):  
Stark Effect ◽  
Overtone Band ◽  
Vibrational Overtone

High resolution study of methane’s 3ν1+ν3 vibrational overtone band

1994 ◽  
Vol 100 (11) ◽  
pp. 7916-7927 ◽  
Author(s):  
Kirk Boraas ◽  
Zhen Lin ◽  
James P. Reilly
Keyword(s):  
High Resolution ◽  
Overtone Band ◽  
Vibrational Overtone ◽  
Resolution Study

scholarly journals Application of the Spectral Structure Parameterization technique: retrieval of total water vapor columns from GOME

2002 ◽  
Vol 2 (4) ◽  
pp. 1097-1130 ◽  
Author(s):  
R. Lang ◽  
J. E. Williams ◽  
W. J. van der Zande ◽  
A. N. Maurellis
Keyword(s):  
Water Vapor ◽  
Scattered Light ◽  
Sampling Technique ◽  
Optical Absorption Coefficient ◽  
Spectral Structure ◽  
Total Water ◽  
Transfer Scheme ◽  
Overtone Band ◽  
Vibrational Overtone ◽  
Reflectivity Spectra

Abstract. We use a recently proposed spectral sampling technique for measurements of atmospheric transmissions called the Spectral Structure Parameterization (SSP) in order to retrieve total water vapor columns (WVC) from reflectivity spectra measured by the Global Ozone Monitoring Experiment (GOME). SSP provides a good compromise between efficiency and speed when performing retrievals on highly structured spectra of narrow-band absorbers like water vapor. We show that SSP can be implemented in a radiative transfer scheme which treats both direct-path absorption and absorption by singly scattered light directly. For the retrieval we exploit a ro-vibrational overtone band of water vapor located in the visible around 590 nm. We compare our results to independent values given by the data assimilation model of ECMWF. In addition, results are compared to those obtained from the more accurate, but slower, Optical Absorption Coefficient Spectroscopy (OACS).

The vibrational overtone spectrum of propyne in the acetylenic CH Δv = 4 region

1992 ◽  
Vol 156 (1) ◽  
pp. 147-153 ◽  
Author(s):  
Zhen Lin ◽  
Kirk Boraas ◽  
James P. Reilly
Keyword(s):  
Vibrational Overtone

Vibrational overtone combination spectroscopy (VOCSY)—a new way of using IR and NIR data

2007 ◽  
Vol 388 (1) ◽  
pp. 179-188 ◽  
Author(s):  
Erik Alm ◽  
Rasmus Bro ◽  
Søren B. Engelsen ◽  
Bo Karlberg ◽  
Ralf J. O. Torgrip
Keyword(s):  
Vibrational Overtone
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