Spin–orbit state selective formation of rare gas chlorides from three‐body ionic‐recombination reactions of Rg+(2P1/2,3/2)+Cl−+He at thermal energy

1991 ◽  
Vol 94 (6) ◽  
pp. 4291-4300 ◽  
Author(s):  
Masaharu Tsuji ◽  
Makoto Furusawa ◽  
Hiroyuki Kouno ◽  
Yukio Nishimura
Keyword(s):  
Thermal Energy ◽  
Rare Gas ◽  
Spin Orbit ◽  
Three Body ◽  
Recombination Reactions ◽  
Selective Formation

Three-body exchange forces in rare-gas crystals

1967 ◽  
Vol 24 (3) ◽  
pp. 163-164 ◽  
Author(s):  
C.E. Swenberg
Keyword(s):  
Rare Gas ◽  
Three Body

Two-body and three-body rare-gas clusters

2017 ◽  
Vol 48 (6) ◽  
pp. 900-905 ◽  
Author(s):  
A. A. Korobitsin ◽  
E. A. Kolganova
Keyword(s):  
Rare Gas ◽  
Gas Clusters ◽  
Three Body ◽  
Rare Gas Clusters

Trajectory study of atomic recombination reactions. VII. Recombination of I and Br atoms

1976 ◽  
Vol 54 (10) ◽  
pp. 1535-1542 ◽  
Author(s):  
D. T. Chang ◽  
George Burns
Keyword(s):  
Potential Energy Surfaces ◽  
Molecular Beam ◽  
Sampling Technique ◽  
Recombination Reaction ◽  
Third Body ◽  
Reaction Proceeds ◽  
Three Body ◽  
Body Potential ◽  
Energy Surfaces ◽  
Recombination Reactions

Classical 3-D trajectory investigation of bromine and iodine atom recombination reactions in He, Ar, and Xe, performed earlier, are extended, using an improved sampling technique, to include a larger number of trajectories and a wider temperature range (200–1500 K). The three body potential energy surfaces used were assumed to be nearly additive, but otherwise were defined by the existing molecular beam and spectroscopic data and contained essentially no arbitrary parameters. The agreement between computed and experimental rate constants is reasonable, and is best if the third body is heavy and reaction proceeds via a bound complex, such as IXe. Orbiting inert gas – recombining atom intermediate dimers, XM*, where X = I or Br, contribute to the overall recombination reaction via XM* + X → X2 + M reaction, provided M is heavy. If M = He, this reaction path is negligible at all temperatures studied, again provided that X = I or Br.

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