Vibrational state dependence of ionic rotational branching ratios in resonance enhanced multiphoton ionization of CH

1989 ◽  
Vol 91 (2) ◽  
pp. 1374-1376 ◽  
Author(s):  
H. Rudolph ◽  
J. A. Stephens ◽  
V. McKoy ◽  
M.‐T. Lee
1980 ◽  
Vol 72 (11) ◽  
pp. 6308-6310 ◽  
Author(s):  
B. E. Cole ◽  
D. L. Ederer ◽  
Roger Stockbauer ◽  
Keith Codling ◽  
Albert C. Parr ◽  
...  

1985 ◽  
Vol 113 (5) ◽  
pp. 429-434 ◽  
Author(s):  
William E. Conaway ◽  
Richard J.S. Morrison ◽  
Richard N. Zare

1988 ◽  
Vol 43 (6) ◽  
pp. 561-571 ◽  
Author(s):  
B. Kleibömer ◽  
D. H. Sutter

Abstract Experimental values for the diagonal elements of the 14N quadrupole coupling tensor derived from analysis of the hyperfine structure of low-J rotational transitions are reported for the two lowest states of the amino wagging mode. They show the expected difference due to averaging over the large amplitude amino wag. A semirigid bender analysis of previously published infrared data provides the inversion angle expectation values for use in a quantum-chemical calculation of the corresponding effective Cou­lomb field gradients at the nitrogen nucleus. The results are compared to those obtained earlier for the related molecules vinylamine, cyanamide and ammonia.


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