scholarly journals Wavelength and vibrational-state dependence of photoelectron angular distributions. Resonance effects in 5σ photoionization of CO

1979 ◽  
Author(s):  
B. E. Cole ◽  
D. L. Ederer ◽  
Albert C. Parr ◽  
Keith Codling ◽  
Roger Stockbauer ◽  
...  
1980 ◽  
Vol 72 (11) ◽  
pp. 6308-6310 ◽  
Author(s):  
B. E. Cole ◽  
D. L. Ederer ◽  
Roger Stockbauer ◽  
Keith Codling ◽  
Albert C. Parr ◽  
...  

The branching ratios for leaving the CO + ion in a particular vibrational level of the ground X 2 Ʃ + state have been determined as functions of photon energy through the n = 3 autoionizing Rydberg state converging to the B 2 Ʃ + state of CO + ; there are substantial differences between theoretical and experimental Franck-Condon factors when ‘on’ resonance. The branching ratios have been converted into absolute partial cross sections by normalizing to existing data obtained by using line sources. The asymmetry parameter β has also been determined for each vibrational level in this spectral range. Considerable variations in both have been observed in the region of this resonance.


2007 ◽  
Vol 76 (1) ◽  
Author(s):  
Jingtao Zhang ◽  
L. D. van Woerkom ◽  
Dong-Sheng Guo ◽  
R. R. Freeman

1994 ◽  
Vol 375 ◽  
Author(s):  
Eric L. Shirley ◽  
Louis J. Terminello ◽  
John E. Klepeis ◽  
F. J. Himpsel

AbstractWe present simulated photoelectron angular distributions (PAD's) for LiF and graphite. The results describe electron photocurrent versus photon energy, electron initial-state energy, and emission angles (leading to identification of two, or three, components of a valence electron's initial crystal momentum). Results are displayed in a fashion greatly facilitated by display analyzers. Earlier experimental results for LiF are confirmed in great detail. We discuss statistical comparison of theoretical and experimental PAD's. Effects of Bragg- diffraction on outgoing photoelectrons and uncertainty in crystal momentum normal to a surface are analyzed. In graphite, the observed lowering of symmetry, from that in a periodic-zone band structure to that seen in the PAD's, is modeled and explained.


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