Computer modeling of molecular liquid mixtures. II. The excess properties of a diatomic Lennard‐Jones model mixture for CO2/C2H6

1987 ◽  
Vol 87 (10) ◽  
pp. 6117-6119 ◽  
Author(s):  
D. Fincham ◽  
N. Quirke ◽  
D. J. Tildesley
Keyword(s):  
Computer Modeling ◽  
Liquid Mixtures ◽  
Model Mixture ◽  
Excess Properties ◽  
Lennard Jones ◽  
Molecular Liquid ◽  
Jones Model

Structure and thermodynamics of molecular liquid mixtures

1986 ◽  
Vol 57 (5) ◽  
pp. 1049-1061 ◽  
Author(s):  
S. Gupta ◽  
J.E. Coon
Keyword(s):  
Liquid Mixtures ◽  
Molecular Liquid

Computer simulations of a Lennard-Jones model for Ar1—x(N2)x: A prototype system for quadrupolar glasses

1998 ◽  
Vol 208-209 (1) ◽  
pp. 293-327 ◽  
Author(s):  
M. H. Müser ◽  
D. Löding ◽  
P. Nielaba ◽  
K. Binder
Keyword(s):  
Computer Simulations ◽  
Prototype System ◽  
Lennard Jones ◽  
Jones Model

New dimensions in salt–solvent mixtures: a 4th evolution of ionic liquids

2018 ◽  
Vol 206 ◽  
pp. 9-28 ◽  
Author(s):  
Douglas R. MacFarlane ◽  
Alison L. Chong ◽  
Maria Forsyth ◽  
Mega Kar ◽  
R. Vijayaraghavan ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Liquid Mixtures ◽  
Solvent Mixtures ◽  
Organic Salts ◽  
Molecular Liquid

The important properties and applications of molecular liquid mixtures with ionic liquids and low melting organic salts are discussed.

Excess properties for binary liquid mixtures of propionic acid with aniline derivatives

1991 ◽  
Vol 69 (3) ◽  
pp. 369-372 ◽  
Author(s):  
Begoña Garcia ◽  
Rafael Alcalde ◽  
José M. Leal
Keyword(s):  
Propionic Acid ◽  
Dipole Moments ◽  
Specific Interaction ◽  
Liquid Mixtures ◽  
Excess Properties ◽  
Free Energies ◽  
Empirical Parameter ◽  
Excess Viscosities ◽  
Different Temperatures ◽  
Mole Volume

Excess viscosities, excess volumes, and excess free energies of activation for flow of the binary mixtures containing propionic acid with aniline, o-toluidine, o-anisidine, and o-chloroaniline were determined at five different temperatures from density and viscosity measurements. Based on the Regular Solutions Theory, the empirical parameter θ was calculated; this parameter is related to the viscosity, and also denotes the extent of the non-ideality of the system. The results obtained suggest the existence of acid–base interactions, as well as the formation of 1:2 complexes for the three first mixtures, and 2:1 complexes for o-chloro-aniline + propionic acid. The extent of the specific interaction decreases with an increase in the strength of the base, and increases with an increase in the dipole moments. The equatioin [Formula: see text] is proposed for predicting the mole volume of the mixtures, V, at any composition, Xi, as a function of the mole volumes of the pure components, Vi. Key words: binary mixture, excess properties, predicting mole volumes, propionic acid.

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