Dielectric friction theory of the viscosity of electrolyte solutions

1986 ◽  
Vol 85 (12) ◽  
pp. 7312-7317 ◽  
Author(s):  
K. Ibuki ◽  
M. Nakahara
Keyword(s):  
Electrolyte Solutions ◽  
Dielectric Friction ◽  
Friction Theory

Dielectric saturation and dielectric friction in electrolyte solutions

1982 ◽  
Vol 77 (12) ◽  
pp. 6189-6196 ◽  
Author(s):  
P. J. Stiles ◽  
J. B. Hubbard ◽  
R. F. Kayser
Keyword(s):  
Electrolyte Solutions ◽  
Dielectric Friction ◽  
Dielectric Saturation

Mechanism of Ion Transport in Cooled and Supercooled Water at High Pressure

1983 ◽  
Vol 22 ◽  
Author(s):  
M. Nakahara ◽  
N. Takisawa ◽  
J. Osugi
Keyword(s):  
Room Temperature ◽  
Pressure Coefficient ◽  
Water Structure ◽  
Continuum Theory ◽  
Supercooled Water ◽  
Ionic Mobility ◽  
Dielectric Friction ◽  
Friction Theory ◽  
The Difference ◽  
The Continuum

ABSTRACTAs predicted by the Hubbard-Onsager continuum dielectric friction theory for ionic mobility in solution, the observed pressure coefficient of the difference ζ between the observed ionic drag coefficient and the Stokes law friction (4πηR), is negative for the small ion Li+ even at low temperatures where the water structure is highly developed. For the large ion Cs+, however, it is positive at any temperature in contrast to the theoretical prediction, its magnitude being larger at lower temperatures and pressures. The anomaly is shown also by the medium-sized ion K+ below room temperature. The passing-through-cavities (PTC) mechanism has been proposed to explain the limitations of the continuum theory.

Rotational diffusion of organic solutes: the role of dielectric friction in polar solvents and electrolyte solutions

1998 ◽  
Vol 77 (1-3) ◽  
pp. 37-60 ◽  
Author(s):  
N. Balabai ◽  
A. Sukharevsky ◽  
I. Read ◽  
B. Strazisar ◽  
M. Kurnikova ◽  
...  
Keyword(s):  
Rotational Diffusion ◽  
Electrolyte Solutions ◽  
Organic Solutes ◽  
Polar Solvents ◽  
Dielectric Friction
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