The limiting concentration dependence of the heat of transport in electrolyte solutions

1986 ◽  
Vol 84 (11) ◽  
pp. 6401-6409 ◽  
Author(s):  
Thomas S. Thacher ◽  
C. Y. Mou ◽  
Udayan Mohanty ◽  
Jeong‐long Lin
1974 ◽  
Vol 14 (6) ◽  
pp. 915-918
Author(s):  
A. M. Sazonov ◽  
V. M. Olevskii ◽  
A. B. Porai-Koshits ◽  
V. N. Skobolev ◽  
G. A. Shmuilovich

1982 ◽  
Vol 47 (12) ◽  
pp. 3171-3176 ◽  
Author(s):  
Miloslav Prchal ◽  
Vladimír Dohnal ◽  
František Veselý

An extensive test of five correlation relations for the concentration dependence of excess enthalpy of non-electrolyte solutions was carried out. The Redlich-Kister, root and reciprocal expansions, the SSF and Wilson equations were used to represent experimental data of 54 systems of different character. For the representation of data of symmetric and slightly asymmetric systems, we recommend the Redlich-Kister polynomial, more asymmetric systems are described excellently by the SSF equation.


1981 ◽  
Vol 36 (12) ◽  
pp. 1367-1370 ◽  
Author(s):  
G. Pálinkás ◽  
E. Kalman

AbstractAqueous cobalt, nickel, zinc, cadmium and aluminium-chloride, -nitrate, -sulphate and PhAsCl solutions at 25 °C were studied by small angle X-ray diffraction. The scattered intensities of chloride, nitrate and CdSO4 solutions show the so-called "prepeak". The concentration dependence of the peak positions is discussed.


1971 ◽  
Vol 26 (11) ◽  
pp. 1885-1887
Author(s):  
Gerhard Höfer

Concentration Dependence of the Thermal Transport of Nitrogen in TantalumIn a temperature gradient nitrogen atoms migrate to the hot region. The heat of transport is negativ and depends on the concentration. If the concentration of the dissolved atoms is higher than 1 at.-%, its value is about -1 kcal/mol, however it increases to -7 kcal/mol for an infinitely dilute solution. This value seems to be more convenient for a comparison with data of other systems and theoretical considerations.


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