Conductance of electrolyte solutions. A modified expression for its concentration dependence

1969 ◽  
Vol 65 (0) ◽  
pp. 3311-3313 ◽  
Author(s):  
R. Fernández-Prini
Keyword(s):  
Concentration Dependence ◽  
Electrolyte Solutions

Concentration dependence of the self-diffusion coefficients of water in electrolyte solutions

1974 ◽  
Vol 14 (6) ◽  
pp. 915-918
Author(s):  
A. M. Sazonov ◽  
V. M. Olevskii ◽  
A. B. Porai-Koshits ◽  
V. N. Skobolev ◽  
G. A. Shmuilovich
Keyword(s):  
Concentration Dependence ◽  
Diffusion Coefficients ◽  
Electrolyte Solutions ◽  
The Self ◽  
Self Diffusion

The limiting concentration dependence of the heat of transport in electrolyte solutions

1986 ◽  
Vol 84 (11) ◽  
pp. 6401-6409 ◽  
Author(s):  
Thomas S. Thacher ◽  
C. Y. Mou ◽  
Udayan Mohanty ◽  
Jeong‐long Lin
Keyword(s):  
Concentration Dependence ◽  
Electrolyte Solutions ◽  
Heat Of Transport

Representation of binary excess enthalpy data

1982 ◽  
Vol 47 (12) ◽  
pp. 3171-3176 ◽  
Author(s):  
Miloslav Prchal ◽  
Vladimír Dohnal ◽  
František Veselý
Keyword(s):  
Experimental Data ◽  
Concentration Dependence ◽  
Excess Enthalpy ◽  
Electrolyte Solutions ◽  
Extensive Test ◽  
Enthalpy Data

An extensive test of five correlation relations for the concentration dependence of excess enthalpy of non-electrolyte solutions was carried out. The Redlich-Kister, root and reciprocal expansions, the SSF and Wilson equations were used to represent experimental data of 54 systems of different character. For the representation of data of symmetric and slightly asymmetric systems, we recommend the Redlich-Kister polynomial, more asymmetric systems are described excellently by the SSF equation.

X-Ray Diffraction on Electrolyte Solutions in the Low Angle Range

1981 ◽  
Vol 36 (12) ◽  
pp. 1367-1370 ◽  
Author(s):  
G. Pálinkás ◽  
E. Kalman
Keyword(s):  
Concentration Dependence ◽  
Small Angle ◽  
Electrolyte Solutions ◽  
Aluminium Chloride ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nickel Zinc ◽  
Cobalt Nickel ◽  
Zinc Cadmium

AbstractAqueous cobalt, nickel, zinc, cadmium and aluminium-chloride, -nitrate, -sulphate and PhAsCl solutions at 25 °C were studied by small angle X-ray diffraction. The scattered intensities of chloride, nitrate and CdSO4 solutions show the so-called "prepeak". The concentration dependence of the peak positions is discussed.

The viscosity of concentrated electrolyte solutions. I. Concentration dependence at fixed temperature

1977 ◽  
Vol 55 (6) ◽  
pp. 1062-1072 ◽  
Author(s):  
Douglas E. Goldsack ◽  
Raymond Franchetto
Keyword(s):  
Concentration Dependence ◽  
Electrolyte Solutions ◽  
Rate Theory ◽  
Absolute Rate ◽  
Fixed Temperature ◽  
Simple Fluids ◽  
Free Energy Of Activation ◽  
Ammonium Halides ◽  
Two Parameters ◽  
B Coefficients

The absolute rate theory of viscosity for simple fluids has been extended to account for the concentration dependence of the viscosity of concentrated single electrolyte solutions (1–10 m region). Graphical and computer techniques for obtaining the two parameters (volume and free energy of activation) which control the concentration dependence of the viscosity of single salt solutions at fixed temperatures are described. The additivity of these parameters for single ions are discussed with reference to the alkali and ammonium halides at 25 °C and the B coefficients of the Jones–Dole equation.

scholarly journals Shear Viscosity of Aqueous Electrolyte Solutions

2019 ◽  
Vol 64 (3) ◽  
pp. 230
Author(s):  
V. M. Makhlaichuk
Keyword(s):  
Concentration Dependence ◽  
Shear Viscosity ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Main Attention ◽  
Debye Theory ◽  
Aqueous Electrolyte Solutions ◽  
Concentration Dependences ◽  
Dipole Ordering ◽  
Exponential Formula

The kinematic shear viscosity of aqueous electrolyte solutions has been studied. The temperature dependence of this parameter is shown to be described by an exponential formula at T < Td and a formula of the argon-like type at T > Td, where Td is the temperature of the dipole ordering, in the whole considered concentration interval. Main attention is focused on the peculiarities in the temperature and concentration dependences of the shear viscosity in the argon-like interval. It is shown that the root-like concentration dependence can appear, only if the Debye theory of dilute electrolyte solutions is applicable. Beyond its validity domain, the series expansion of the kinematic shear viscosity in the concentration parameter should have an analytical character. The latter behavior is inherent in the concentration dependence of the shear viscosity in the majority of experiments. The error of reproducing the experimental data did not exceed the experimental one, i.e. it was smaller than 4–5%.

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