Erratum: Vibrational predissociation and infrared spectrum of the Ar–HCl van der Waals molecule [J. Chem. Phys. 81, 2357 (1984)]

1984 ◽  
Vol 81 (12) ◽  
pp. 6413-6413 ◽  
Author(s):  
Jeremy M. Hutson
Keyword(s):  
Infrared Spectrum ◽  
Van Der Waals ◽  
Chem Phys ◽  
Vibrational Predissociation

scholarly journals Consecutive Vibrational Redistribution and Predissociation Processes in s-Tetrazine–Argon Van Der Waals Complexes

1983 ◽  
Vol 2 (3-4) ◽  
pp. 125-135 ◽  
Author(s):  
J. J. F. Ramaekers ◽  
L. B. Krijnen ◽  
H. J. Lips ◽  
J. Langelaar ◽  
R. P. H. Rettschnick
Keyword(s):  
Decay Time ◽  
Van Der Waals ◽  
Stagnation Pressure ◽  
Van Der Waals Complexes ◽  
Supersonic Expansion ◽  
Vibrational Predissociation ◽  
Out Of Plane ◽  
Spectrally Resolved ◽  
Plane Mode

s-Tetrazine argon complexes T−Arn (n = 1, 2) are formed in a supersonic expansion of argon seeded with s-tetrazine. The expansion was conducted through a nozzle of 50 or 100 μm with an argon stagnation pressure between 1 and 1.5 bar. From spectrally resolved measurements it is clear that vibrational redistribution processes as well as vibrational predissociation processes take place after SVL excitation within the complex.From rise and decay time experiments it can be concluded, that after excitation of the 6a1 complex level, the above mentioned processes are consecutive and not parallel. It appears that the out of plane mode 16a couples with the Van der Waals stretching mode. The predissociation rate of the 16a2 complex is observed to be 2.3 × 109 s−1.

Infrared Vibrational Predissociation Spectroscopy of van der Waals Clusters

1983 ◽  
pp. 271-272
Author(s):  
J.-M. Zellweger ◽  
J.-M. Philippoz ◽  
P. Melinon ◽  
R. Monot ◽  
H. van den Bergh
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Clusters ◽  
Vibrational Predissociation
Sign in / Sign up

Export Citation Format

Share Document