H+D2 reaction dynamics. Determination of the product state distributions at a collision energy of 1.3 eV

1984 ◽  
Vol 80 (9) ◽  
pp. 4142-4156 ◽  
Author(s):  
Ernesto E. Marinero ◽  
Charles T. Rettner ◽  
R. N. Zare
Keyword(s):  
Collision Energy ◽  
Reaction Dynamics ◽  
Product State

Influence of the Collision Energy on the O(1D) + RH → OH(X2Π) + R (RH = CH4, C2H6, C3H8) Reaction Dynamics:  A Laser-Induced Fluorescence and Quasiclassical Trajectory Study

2000 ◽  
Vol 104 (3) ◽  
pp. 521-529 ◽  
Author(s):  
Miguel González ◽  
María P. Puyuelo ◽  
Jordi Hernando ◽  
R. Sayós ◽  
Pedro A. Enríquez ◽  
...  
Keyword(s):  
Collision Energy ◽  
Reaction Dynamics ◽  
Laser Induced Fluorescence

scholarly journals Time-Resolved Macromolecular Crystallography at Pulsed X-ray Sources

2019 ◽  
Vol 20 (6) ◽  
pp. 1401 ◽  
Author(s):  
Marius Schmidt
Keyword(s):  
Structural Biology ◽  
Free Electron ◽  
Reaction Dynamics ◽  
X Rays ◽  
Free Electron Lasers ◽  
Macromolecular Crystallography ◽  
Time Resolved ◽  
X Ray ◽  
Methodological Aspects

The focus of structural biology is shifting from the determination of static structures to the investigation of dynamical aspects of macromolecular function. With time-resolved macromolecular crystallography (TRX), intermediates that form and decay during the macromolecular reaction can be investigated, as well as their reaction dynamics. Time-resolved crystallographic methods were initially developed at synchrotrons. However, about a decade ago, extremely brilliant, femtosecond-pulsed X-ray sources, the free electron lasers for hard X-rays, became available to a wider community. TRX is now possible with femtosecond temporal resolution. This review provides an overview of methodological aspects of TRX, and at the same time, aims to outline the frontiers of this method at modern pulsed X-ray sources.

scholarly journals Reaction dynamics of the 4-methylphenyl radical (C6H4CH3; p-tolyl) with isoprene (C5H8) – formation of dimethyldihydronaphthalenes

2014 ◽  
Vol 16 (31) ◽  
pp. 16805-16814 ◽  
Author(s):  
Beni B. Dangi ◽  
Tao Yang ◽  
Ralf I. Kaiser ◽  
Alexander M. Mebel
Keyword(s):  
Electronic Structure ◽  
Molecular Beam ◽  
Collision Energy ◽  
Reaction Dynamics ◽  
Electronic Structure Calculations ◽  
Single Collision ◽  
Collision Condition ◽  
Structure Calculations ◽  
Beam Technique ◽  
Crossed Molecular Beam

Reaction dynamics and energetics of 4-methylphenyl radical with isoprene are reported under single collision condition at collision energy of 58 kJ mol−1 by exploiting the crossed molecular beam technique and electronic structure calculations.

scholarly journals Reaction dynamics of H+O2 at 1.6 eV collision energy

1989 ◽  
Vol 156 (1) ◽  
pp. 7-13 ◽  
Author(s):  
Michael J. Bronikowski ◽  
Rong Zhang ◽  
David J. Rakestraw ◽  
Richard N. Zare
Keyword(s):  
Collision Energy ◽  
Reaction Dynamics

scholarly journals Chirality Affecting Reaction Dynamics of HgS Nanostructures Simultaneously Visualized in Real and Reciprocal Space

2021 ◽  
Author(s):  
Zetan Cao ◽  
Jia He ◽  
Zhiwen Liu ◽  
Haoran Zhang ◽  
Bin Chen
Keyword(s):  
Electron Beam ◽  
Asymmetric Synthesis ◽  
Reaction Dynamics ◽  
Reciprocal Space ◽  
In Situ Observation ◽  
Size Dependent ◽  
Electron Beam Excitation ◽  
Evaporation Dynamics ◽  
Induced Changes

Abstract Chirality involved reactions enable to probe features in the fields of asymmetric synthesis and catalysis, which allow to gain insight into the fundamental mechanisms of topochemically controlled reactions. However, in situ observation of the chirality-associated reaction dynamics with simultaneous structural determination of new features has been lacking. Here, we report the direct visualization of the electron-beam-stimulated reaction dynamics of HgS nanostructures with chiral and achiral morphologies simultaneously in both real and reciprocal space. Under the electron-beam excitation of HgS nanostructures, the formation and evaporation dynamics of Hg nanodroplets were vividly pictured while the reciprocal space imaging revealed the structural transformation from monocrystalline to polycrystalline. Such induced changes were size-dependent, which were slowed down when involving the chirality in the nanostructures. The finding offers a fundamental understanding of topochemically controlled reaction mechanisms and holds promise of tuning asymmetric synthesis for catalysis related applications.

Sign in / Sign up

Export Citation Format

Share Document