Absolute rate constants and temperature dependencies for the gas phase reactions of H atoms with propene and the butenes in the temperature range 298 to 445 K

1982 ◽  
Vol 77 (8) ◽  
pp. 3994-3997 ◽  
Author(s):  
G. W. Harris ◽  
J. N. Pitts
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Absolute Rate ◽  
Gas Phase Reactions ◽  
Temperature Range

The reactions of O(3P) with the butanols

1983 ◽  
Vol 61 (12) ◽  
pp. 2716-2720 ◽  
Author(s):  
John M. Roscoe
Keyword(s):  
Free Energy ◽  
Gas Phase ◽  
Rate Constants ◽  
Substrate Concentration ◽  
Kinetic Data ◽  
Absolute Rate ◽  
Gas Phase Reactions ◽  
Linear Free Energy ◽  
Different Types ◽  
Energy Relations

The reactions of O(3P) with the butanols were studied kinetically as a function of temperature and substrate concentration. The absolute rate constants for the gas phase reactions, in the units M−1 s−1, obey the following relations.[Formula: see text]The results suggest that although the α-CH bond in these alcohols is the most reactive one, reaction of O(3P) with other CH bonds in the alcohols is also appreciable. The kinetic data for these and other alcohols are separated into contributions from the different types of CH bonds and the results are discussed in terms of linear free energy relations.

Rate constants for the gas-phase reactions of cyclo-CXCXCF2CF2– (X=H, F) with OH radicals at a temperature range of 253–328K

2013 ◽  
Vol 572 ◽  
pp. 21-25 ◽  
Author(s):  
Xiaoqing Jia ◽  
Liang Chen ◽  
Junji Mizukado ◽  
Shuzo Kutsuna ◽  
Kazuaki Tokuhashi
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Oh Radicals ◽  
Gas Phase Reactions ◽  
Temperature Range

scholarly journals Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes

2003 ◽  
Vol 3 (6) ◽  
pp. 2233-2307 ◽  
Author(s):  
R. Atkinson
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Relative Rate ◽  
Oh Radicals ◽  
Gas Phase Reactions ◽  
Temperature Dependent ◽  
Temperature Range ◽  
Dependent Rate ◽  
Temperature Ranges ◽  
Kinetics Of

Abstract. The available database concerning rate constants for gas-phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented over the entire temperature range for which measurements have been made (~180-2000 K). Measurements made using relative rate methods are re-evaluated using recent rate data for the reference compound (generally recommendations from this review). In general, whenever more than one study has been carried out over an overlapping temperature range, recommended rate constants or temperature-dependent rate expressions are presented. The recommended 298 K rate constants, temperature-dependent parameters, and temperature ranges over which these recommendations are applicable are listed in Table 1.

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