Matrix isolation infrared and mass spectrometric studies of the vapors formed by the thermal decomposition of Te6O11Cl2

1980 ◽  
Vol 72 (9) ◽  
pp. 5192-5201 ◽  
Author(s):  
G. H. Westphal ◽  
F. Rosenberger ◽  
P. R. Cunningham ◽  
L. L. Ames
Keyword(s):  
Thermal Decomposition ◽  
Matrix Isolation ◽  
Mass Spectrometric

Mass Spectrometric Studies of the Thermal Decomposition of Poly(carbon monofluoride)

1965 ◽  
Vol 4 (11) ◽  
pp. 1639-1641 ◽  
Author(s):  
A. K. Kuriakose ◽  
J. L. Margrave
Keyword(s):  
Thermal Decomposition ◽  
Mass Spectrometric

Mass spectrometric studies of chemical reactions in shock waves: the thermal decomposition of nitrous oxide

1969 ◽  
Vol 47 (4) ◽  
pp. 521-538 ◽  
Author(s):  
S. C. Barton ◽  
J. E. Dove
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Rate Coefficient ◽  
Mass Spectrometric Study ◽  
Mass Spectrometric ◽  
Unimolecular Decomposition ◽  
Reflected Shock ◽  
Secondary Reactions ◽  
Gas Reactions ◽  
Collision Mechanism

Apparatus for the mass spectrometric study of rapid gas reactions in reflected shock waves is described. This apparatus has been applied to the thermal decomposition of 2% N2O in Kr at total gas concentrations of about 1.6 × 10−6 mole cm−3, in the temperature range 1800 to 2800 °K. The principal products of the reaction were found to be N2, O2, NO, and O. The rate coefficient for the unimolecular decomposition of N2O was calculated from the experimental data, and the rates of the secondary reactions between O and N2O were estimated. The possibility of the occurrence of a "weak collision" mechanism in the unimolecular reaction of N2O is discussed.

The thermal decomposition of diethyl ether. II. Analytical survey of the reaction products as a function of reaction conditions

1958 ◽  
Vol 245 (1240) ◽  
pp. 40-48 ◽  
Keyword(s):  
Thermal Decomposition ◽  
Rate Constants ◽  
Vapour Phase ◽  
Mass Spectrometric ◽  
Spectrometric Analysis ◽  
Reaction Products ◽  
Reaction Conditions ◽  
True Rate ◽  
Carbon Tetrafluoride ◽  
Pressure Changes

By mass-spectrometric analysis combined with vapour-phase chromatography the reaction products from the thermal decomposition of ether have been determined at various stages of the reaction (uninhibited and inhibited by nitric oxide) for initial ether pressures of 80 to 1000 mm. The effects of added hydrogen and of carbon tetrafluoride on the composition of the products have also been examined. No major changes in the chemistry of the reaction occur with these variations in conditions. Factors are given for calculating true rate constants from pressure changes accompanying the reaction. Corrected values of rate constants vary with the conditions in the same way as the values derived from uncorrected pressure changes, the correspondence being close for the uninhibited reaction.

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