Fluorescence excitation spectrum of s‐tetrazine cooled in a supersonic free jet: Van der waals complexes and isotopic species

1978 ◽  
Vol 68 (5) ◽  
pp. 2487-2491 ◽  
Author(s):  
Richard E. Smalley ◽  
Lennard Wharton ◽  
Donald H. Levy ◽  
Dean W. Chandler
Keyword(s):  
Excitation Spectrum ◽  
Van Der Waals ◽  
Fluorescence Excitation Spectrum ◽  
Van Der Waals Complexes ◽  
Fluorescence Excitation ◽  
Free Jet ◽  
Isotopic Species

Free‐jet fluorescence excitation spectrum of trans, trans‐1,3,5,7‐octatetraene

1981 ◽  
Vol 75 (9) ◽  
pp. 4338-4342 ◽  
Author(s):  
Lou Ann Heimbrook ◽  
Jonathan E. Kenny ◽  
Bryan E. Kohler ◽  
Gary W. Scott
Keyword(s):  
Excitation Spectrum ◽  
Fluorescence Excitation Spectrum ◽  
Fluorescence Excitation ◽  
Free Jet

The fluorescence excitation spectrum of s-tetrazine cooled in a supersonic free jet

1977 ◽  
Vol 66 (3) ◽  
pp. 375-388 ◽  
Author(s):  
Richard E. Smalley ◽  
Lennard Wharton ◽  
Donald H. Levy ◽  
Dean W. Chandler
Keyword(s):  
Excitation Spectrum ◽  
Fluorescence Excitation Spectrum ◽  
Fluorescence Excitation ◽  
Free Jet

Fluorescence excitation spectrum of the Si–Ar van der Waals complex

1990 ◽  
Vol 92 (5) ◽  
pp. 2828-2836 ◽  
Author(s):  
C. Dedonder‐Lardeux ◽  
C. Jouvet ◽  
M. Richard‐Viard ◽  
D. Solgadi
Keyword(s):  
Excitation Spectrum ◽  
Van Der Waals ◽  
Fluorescence Excitation Spectrum ◽  
Fluorescence Excitation ◽  
Van Der Waals Complex

Fluorescence excitation spectrum of silver–argon van der Waals complex

1991 ◽  
Vol 94 (3) ◽  
pp. 1759-1764 ◽  
Author(s):  
C. Jouvet ◽  
C. Lardeux‐Dedonder ◽  
S. Martrenchard ◽  
D. Solgadi
Keyword(s):  
Excitation Spectrum ◽  
Van Der Waals ◽  
Fluorescence Excitation Spectrum ◽  
Fluorescence Excitation ◽  
Van Der Waals Complex

scholarly journals Proton Tunneling In 5-Chlorotropolone-M1 (M = Kr, Xe, CH4) Van Der Waals Complexes

1995 ◽  
Vol 15 (2-4) ◽  
pp. 229-247
Author(s):  
Hiroshi Sekiya ◽  
Taiji Nakajima ◽  
Hidenori Hamabe ◽  
Akira Mori ◽  
Hitoshi Takeshita ◽  
...  
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Excitation Spectra ◽  
Fluorescence Excitation ◽  
Proton Tunneling ◽  
Tunneling Splitting ◽  
Free Jet ◽  
Tunneling Splittings ◽  
Fluorescence Excitation Spectra ◽  
Intramolecular Motions

The S1-S0 fluorescence excitation spectra of 5-chlorotropolone-M1 (M = Kr, Xe, CH4) van der Waals (vdW) complexes in the region near the electronic origin have been measured in a supersonic free jet to investigate the effect of the vdW interactions on proton tunneling. Tunneling splittings have been observed in the vdW vibrations as well as in the 000 transitions of the Kr and Xe complexes. The 000 tunneling splitting of the 5-chlorotropolone-(CH4)1 complex is significantly smaller than those of the Kr and Xe complexes. It has been suggested that the vdW vibrations couple with intramolecular motions, leading to a higher potential energy barrier to tunneling in the CH4 complex. The results of the 5- chlorotropolone complexes have been compared to those of the tropolone complexes.

Sign in / Sign up

Export Citation Format

Share Document