Photoelectron spectra of polynuclear aromatics. V. Correlations with ultraviolet absorption spectra in the catacondensed series

1977 ◽  
Vol 66 (2) ◽  
pp. 828-845 ◽  
Author(s):  
W. Schmidt
Keyword(s):  
Absorption Spectra ◽  
Ultraviolet Absorption ◽  
Photoelectron Spectra ◽  
Polynuclear Aromatics

On the photoelectron and ultraviolet spectra of molecules containing a divalent sulfur atom and a carbonyl group separated by a methylene group

1976 ◽  
Vol 54 (19) ◽  
pp. 3026-3030 ◽  
Author(s):  
P. R. Olivato ◽  
H. Viertler ◽  
B. Wladislaw ◽  
K. C. Cole ◽  
C. Sandorfy
Keyword(s):  
Carbonyl Group ◽  
Absorption Spectra ◽  
Sulfur Atom ◽  
Lone Pair ◽  
Ultraviolet Absorption ◽  
Photoelectron Spectra ◽  
Ultraviolet Spectra ◽  
Methylene Group ◽  
Divalent Sulfur

Photoelectron spectra show that in CH3SCH2COCH3 the sulfur and carbonyl lone pair orbitals [Formula: see text] are both stabilized with respect to the compounds containing S or CO only. This is in keeping with the observed values of the basicity constants. The ultraviolet absorption spectra contain the expected [Formula: see text] and [Formula: see text] bands and give evidence for a significant amount of mixing between the excited orbitals.

FAR ULTRAVIOLET ABSORPTION SPECTRA OF N3AND N2+GENERATED BY ELECTRONS IMPACTING GASEOUS N2

2013 ◽  
Vol 779 (1) ◽  
pp. 40 ◽  
Author(s):  
Yu-Jong Wu ◽  
Hui-Fen Chen ◽  
Shiang-Jiun Chuang ◽  
Tzu-Ping Huang
Keyword(s):  
Absorption Spectra ◽  
Ultraviolet Absorption ◽  
Far Ultraviolet

scholarly journals ULTRAVIOLET ABSORPTION SPECTRA AT REDUCED TEMPERATURES

1950 ◽  
Vol 187 (1) ◽  
pp. 299-312
Author(s):  
R.L. Sinsheimer ◽  
J.F. Scott ◽  
J.R. Loofbourow
Keyword(s):  
Absorption Spectra ◽  
Ultraviolet Absorption

ULTRAVIOLET ABSORPTION SPECTRA AND ACIDITIES OF ISOMERIC THIATRIAZOLE AND TETRAZOLE DERIVATIVES

1959 ◽  
Vol 37 (3) ◽  
pp. 563-574 ◽  
Author(s):  
Eugene Lieber ◽  
J. Ramachandran ◽  
C. N. R. Rao ◽  
C. N. Pillai
Keyword(s):  
Absorption Spectra ◽  
Absorption Maximum ◽  
Dipole Moments ◽  
Ring System ◽  
Ultraviolet Absorption ◽  
Characteristic Absorption ◽  
Tetrazole Derivatives

The ultraviolet absorption spectra of 5-(substituted)amino-1,2,3,4-thiatriazoles and the corresponding isomeric 1-substituted-tetrazoline-5-thiones have been studied. The spectra and the dipole moments of the 5-(substituted)amino-1,2,3,4-thiatriazoles eliminate the possibility of meso-ionic structures for these compounds. The dipole moments of 5-amino-, 5-methylamino-, and 5-dimethylamino-1,2,3,4-thiatriazole were all high but approximately of the same value (5.77 to 5.84 D). This suggests that the amino thiatriazoles are best represented by conventional covalent structures with significant ionic resonance contributions. The thiatriazole ring system exhibits a characteristic absorption maximum at 250–255 mμ and an electron-withdrawing effect approximately equal to the tetrazolyl ring system. The tetrazolinethionolyl ring system is similarly electron-withdrawing. The relative acidities of the 1-substituted-tetrazoline-5-thiones and the 5-alkylmercaptotetrazoles have also been studied and the results support the observations made on the basis of their ultraviolet absorption spectra.

Ultraviolet absorption spectra of monomer and dimer of benzoic acid

1962 ◽  
Vol 8 (1-6) ◽  
pp. 257-275 ◽  
Author(s):  
Haruo Hosoya ◽  
Jiro Tanaka ◽  
Saburo Nagakura
Keyword(s):  
Benzoic Acid ◽  
Absorption Spectra ◽  
Ultraviolet Absorption
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