Structural, Thermal, Electrical and Magnetic Properties of PVA: Mn[sup 2+] and PVA: Ni[sup 2+] Polymer Films

2011 ◽  
Author(s):  
M. Obula Reddy ◽  
S. Buddhudu ◽  
P. K. Bajpai ◽  
K. S. Ojha ◽  
K. N. Singh
2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
M. Obula Reddy ◽  
B. Chandra Babu

Polymer films of PVA:Gd3+ and PVA:Ho3+ have been synthesized by a solution casting method in order to study their structural, optical, electrical, and magnetic properties. The semicrystalline nature of the polymer films has been confirmed from XRD analysis. The FTIR analysis confirms the complex formation of the polymer with the metal ions. Dielectric studies of these films have also been carried out at various set temperatures in the frequency from 100 Hz to 1 MHz for carrying out impedance spectroscopy analysis to evaluate the electrical conductivity which arises due to a single conduction mechanism and thus to have a single semicircle pattern from these polymer films. The DC electrical conductivity increases with an increase in the temperature and it could be due to high mobility of free charges (polarons and free ions) at higher temperatures. The conductivity trend follows the Arrhenius equation for PVA:Gd3+ and for PVA:Ho3+ polymer films. PVA:Gd3+ polymer films show ferromagnetic nature, and PVA:Ho3+ polymer films have revealed paramagnetic nature based on the trends noticed in the magnetic characteristic profiles.


Author(s):  
A.R. Pelton ◽  
A.F. Marshall ◽  
Y.S. Lee

Amorphous materials are of current interest due to their desirable mechanical, electrical and magnetic properties. Furthermore, crystallizing amorphous alloys provides an avenue for discerning sequential and competitive phases thus allowing access to otherwise inaccessible crystalline structures. Previous studies have shown the benefits of using AEM to determine crystal structures and compositions of partially crystallized alloys. The present paper will discuss the AEM characterization of crystallized Cu-Ti and Ni-Ti amorphous films.Cu60Ti40: The amorphous alloy Cu60Ti40, when continuously heated, forms a simple intermediate, macrocrystalline phase which then transforms to the ordered, equilibrium Cu3Ti2 phase. However, contrary to what one would expect from kinetic considerations, isothermal annealing below the isochronal crystallization temperature results in direct nucleation and growth of Cu3Ti2 from the amorphous matrix.


2018 ◽  
Vol 44 (7) ◽  
pp. 595-598 ◽  
Author(s):  
V. V. Balashev ◽  
K. S. Ermakov ◽  
L. A. Chebotkevich ◽  
V. V. Korobtsov

Author(s):  
Hasitha Ganegoda ◽  
Soham Mukherjee ◽  
Beihai Ma ◽  
Daniel T. Olive ◽  
James H. McNeely ◽  
...  

2017 ◽  
Vol 190 (5-6) ◽  
pp. 267-276
Author(s):  
C. A. Estrada Rodriguez ◽  
J. L. Pimentel ◽  
A. M. Turatti ◽  
L. F. Lopes ◽  
R. F. Lopes ◽  
...  

2020 ◽  
pp. 157973
Author(s):  
Adrian Gudwański ◽  
Ewa Malicka ◽  
Tadeusz Groń ◽  
Małgorzata Karolus ◽  
Monika Oboz ◽  
...  

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