Communication: Determination of the bond dissociation energy (D0) of the water dimer, (H2O)2, by velocity map imaging

2011 ◽  
Vol 134 (21) ◽  
pp. 211101 ◽  
Author(s):  
Blithe E. Rocher-Casterline ◽  
Lee C. Ch'ng ◽  
Andrew K. Mollner ◽  
Hanna Reisler
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Water Dimer ◽  
Velocity Map Imaging ◽  
Bond Dissociation

Determination of the heat of formation of trimethylindium and calculation of the mean In—CH3 bond dissociation energy

1968 ◽  
Vol 46 (10) ◽  
pp. 1633-1634 ◽  
Author(s):  
W. D. Clark ◽  
S. J. W. Price
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Chloroform Solution ◽  
Kinetic Studies ◽  
Heat Of Formation ◽  
Enthalpy Of Reaction ◽  
Kcal Mole ◽  
Bond Dissociation ◽  
The Mean

The enthalpy of reaction of In(CH3)3,c with a chloroform solution of bromine is −162.5 kcal mole−1. With this value ΔHf0298[In(CH3)3,c] = 29.5 kcal mole−1 and ΔHf0298[In(CH3)3,g] = 41.1 kcal mole−1. Combining the latter with ΔHf0298[CH3,g] = 33.2 kcal mole−1 and ΔHf0298[In,g] = 58.2 kcal mole−1 then gives E(In—CH3) = 38.9 kcal mole−1. From previous kinetic studies D[(CH3)2In—CH3] + D[In—CH3] = 87.9 kcal mole−1. Hence D[CH3In—CH3] = 28.8 kcal mole−1.

Sign in / Sign up

Export Citation Format

Share Document