An analysis of the high‐temperature relaxation in polycrystalline magnetite

1994 ◽  
Vol 75 (10) ◽  
pp. 6100-6102
Author(s):  
J. Castro ◽  
D. Martinez ◽  
J. Rivas ◽  
H. J. Blythe
1985 ◽  
Vol 46 (C10) ◽  
pp. C10-367-C10-370 ◽  
Author(s):  
S. BELHAS ◽  
A. RIVIERE ◽  
J. WOIRGARD ◽  
J. VERGNOL ◽  
J. DE FOUQUET

1987 ◽  
Vol 42 (6) ◽  
pp. 556-558 ◽  
Author(s):  
Ch. Zylka ◽  
G. Vojta

We investigate the problem of distributing a given amount of heat among three systems under the following conditions: The systems are able to exhibit negative Kelvin temperatures, and heat equalization always fulfills a harmonic mixing rule T = 2T(1) · T(2)/(T(1) + T(2)). Just this happens for spin systems in the high temperature approximation.


1974 ◽  
Vol 16 (4) ◽  
pp. 993-999 ◽  
Author(s):  
Ye.A. Sidorovich ◽  
G.N. Pavlov ◽  
A.I. Marei

1994 ◽  
Vol 49 (17) ◽  
pp. 11550-11559 ◽  
Author(s):  
C.-S. Tu ◽  
I. G. Siny ◽  
V. H. Schmidt

2021 ◽  
Author(s):  
RIDA AHMED ◽  
Shuting Wang ◽  
Sajid ur Rehman ◽  
Jie Sun ◽  
Jin Wang ◽  
...  

Abstract Doped ceria, i.e. Ce1-xMxO2-d with M being dopant metal, has been a focus of great attention for SOFCs due to its high oxygen conduction. In the past literature, the dielectric relaxations in these materials have been ascribed to be caused by defect associates (MCeʺ-Vö) possessing different MCeʺ and Vö distances. But we believe that with changing measurement and analysis techniques it is necessary to invest our time to re-examine the already reported materials and to again take a detailed investigation of the underlying phenomenon behind their dielectric relaxations. Thus, we have used solid-state reaction to prepare Ce1-xMxO2-δ with M=Ca, Sm, and Nd in x=0.1, 0.2, and 0.3 ratios, respectively. The as-prepared and post annealed samples were tested for dielectric properties from 300-1080 K with varying frequencies. The low-temperature relaxation (R1) was argued to be a Maxwell-Wagner relaxation caused by humidity sensitivity. The high-temperature relaxation (R2) was ascribed to be caused by hopping motion of oxygen vacancies. This fact was also supported by detailed analysis of impedance spectra. While, according to the previous reports this relaxation is because of oxygen-vacancy-dopant defect pair.


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