Toward Oxide Scale Behavior Management At High Temperature

2011 ◽  
Author(s):  
R. Deltombe ◽  
M. Dubar ◽  
A. Dubois ◽  
L. Dubar ◽  
Francisco Chinesta ◽  
...  
Author(s):  
Michal Krzyzanowski ◽  
John H. Beynon ◽  
Didier C. J. Farrugia

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3764
Author(s):  
Krzysztof Aniołek ◽  
Adrian Barylski ◽  
Marian Kupka

High-temperature oxidation was performed at temperatures from 600 to 750 °C over a period of 24 h and 72 h. It was shown in the study that the oxide scale became more homogeneous and covered the entire surface as the oxidation temperature increased. After oxidation over a period of 24 h, the hardness of the produced layers increased as the oxidation temperature increased (from 892.4 to 1146.6 kgf/mm2). During oxidation in a longer time variant (72 h), layers with a higher hardness were obtained (1260 kgf/mm2). Studies on friction and wear characteristics of titanium were conducted using couples with ceramic balls (Al2O3, ZrO2) and with high-carbon steel (100Cr6) balls. The oxide films produced at a temperature range of 600–750 °C led to a reduction of the wear ratio value, with the lowest one obtained in tests with the 100Cr6 steel balls. Frictional contact of Al2O3 balls with an oxidized titanium disc resulted in a reduction of the wear ratio, but only for the oxide scales produced at 600 °C (24 h, 72 h) and 650 °C (24 h). For the ZrO2 balls, an increase in the wear ratio was observed, especially when interacting with the oxide films obtained after high-temperature oxidation at 650 °C or higher temperatures. The increase in wear intensity after titanium oxidation was also observed for the 100Cr6 steel balls.


2009 ◽  
Vol 51 (2) ◽  
pp. 309-315 ◽  
Author(s):  
Lucía Suárez ◽  
Yvan Houbaert ◽  
Xavier Vanden Eynde ◽  
Rafael Colás

CORROSION ◽  
10.5006/2802 ◽  
2018 ◽  
Vol 74 (9) ◽  
pp. 984-1000 ◽  
Author(s):  
Esmaeil Sadeghi ◽  
Nicolaie Markocsan ◽  
Tanvir Hussain ◽  
Matti Huhtakangas ◽  
Shrikant Joshi

NiCrMo coatings with and without dispersed SiO2 were deposited using high-velocity air-fuel technique. Thermogravimetric experiments were conducted in 5% O2 + 500 vppm HCl + N2 with and without a KCl deposit at 600°C for up to 168 h. The SiO2-containing coating showed lower weight change as a result of formation of a protective and adherent Cr-rich oxide scale. SiO2 decelerated short-circuit diffusion of Cr3+ through scale’s defects, e.g., vacancies, and promoted the selective oxidation of Cr to form the protective Cr-rich oxide scale. Furthermore, the presence of SiO2 led to less subsurface depletion of Cr in the coating, and accordingly less corrosion of the substrate. The formed corrosion product on the SiO2-free coating was highly porous, non-adherent, and thick.


2018 ◽  
Vol 28 (1) ◽  
pp. 463-474 ◽  
Author(s):  
Amir Motallebzadeh ◽  
Shaikh Asad Ali Dilawary ◽  
Erdem Atar ◽  
Huseyin Cimenoglu

2008 ◽  
Vol 59 (5) ◽  
pp. 380-388 ◽  
Author(s):  
H. Ackermann ◽  
G. Teneva-Kosseva ◽  
H. Köhne ◽  
K. Lucka ◽  
S. Richter ◽  
...  

2008 ◽  
Vol 595-598 ◽  
pp. 1127-1134 ◽  
Author(s):  
Frédéric Riffard ◽  
Henri Buscail ◽  
F. Rabaste ◽  
Eric Caudron ◽  
Régis Cueff ◽  
...  

Chromia-forming steels are excellent candidates to resist to high temperature oxidizing atmospheres because they form protective oxide scales. The oxide scale growth mechanisms are studied by exposing AISI 304 stainless steel to high temperature conditions in air, and the analyses were carried out by means of thermogravimetry and in situ X-rays diffraction. The in situ XRD analyses carried out during high temperature AISI 304 steel oxidation in air reveals the accelerated growth of iron-containing oxides such as hematite Fe2O3 and iron-chromite FeCr2O4, when the initial germination of the oxide layer contains the presence of a manganese-containing spinel compound (1000°C). When the initial growth shows the only chromia formation (800°C), hematite formation appears differed in time. Protection against corrosion is thus increased when the initial germination of manganese-containing spinel oxide is inhibited in the oxide scale.


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