Studies on oxygen chemical surface exchange and electrical conduction in thin film nanostructured titania at high temperatures and varying oxygen pressure

2011 ◽  
Vol 134 (1) ◽  
pp. 014704 ◽  
Author(s):  
Changhyun Ko ◽  
Annamalai Karthikeyan ◽  
Shriram Ramanathan
1987 ◽  
Author(s):  
K. Sugihara ◽  
M. S. Dresselhaus

2021 ◽  
pp. 413174
Author(s):  
Yuxin Shi ◽  
Pengwei Zhai ◽  
Lixiang Meng ◽  
Zongyin Huang ◽  
Guoqiang Li

2009 ◽  
Vol 289-292 ◽  
pp. 775-782 ◽  
Author(s):  
Zbigniew Jurasz ◽  
Krzysztof Adamaszek ◽  
Romuald Janik ◽  
Zbigniew Grzesik ◽  
Stanisław Mrowec

Detailed investigations of nonstoichiometry as well as chemical and self-diffusion in nickel oxide have shown that doubly ionised cation vacancies and electron holes are the predominant defects in this material. The present work is an attempt to demonstrate that aliovalent impurities (Cr, Al, Na and Li) may considerably influence the concentration of these defects and, consequently, the oxidation rate of nickel at high temperatures. It has been shown that small amounts of tri-valent impurities (Cr, Al) bring about an increase of the oxidation rate, while mono-valent ones (Li, Na) decrease the rate of oxidation. These phenomena may satisfactorily be explained in terms of a doping effect. All experiments have been carried out as a function of temperature (1373-1673 K) and oxygen pressure (1-105 Pa) and consequently, it was possible to determine the influence of impurities not only on the oxidation rate but also on the activation energy of reaction and its pressure dependence. The results of these investigations could again be elucidated in terms of doping effect.


2019 ◽  
Vol 35 (1) ◽  
pp. 2409-2416 ◽  
Author(s):  
Yan Chen ◽  
Woo Chul Jung ◽  
Yener Kuru ◽  
Harry L. Tuller ◽  
Bilge Yildiz
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