scholarly journals Quantitative analyses of oxidation states for cubic SrMnO3 and orthorhombic SrMnO2.5 with electron energy loss spectroscopy

2010 ◽  
Vol 108 (12) ◽  
pp. 124903 ◽  
Author(s):  
S. Kobayashi ◽  
Y. Tokuda ◽  
T. Mizoguchi ◽  
N. Shibata ◽  
Y. Sato ◽  
...  
Keyword(s):  
Energy Loss ◽  
Electron Energy ◽  
Electron Energy Loss Spectroscopy ◽  
Oxidation States ◽  
Quantitative Analyses ◽  
Electron Energy Loss

The determination of Ti, Mn and Fe oxidation states in minerals by electron energy-loss spectroscopy

1985 ◽  
Vol 18 (1-4) ◽  
pp. 285-289 ◽  
Author(s):  
Max T. Otten ◽  
Barbara Miner ◽  
James H. Rask ◽  
Peter R. Buseck
Keyword(s):  
Energy Loss ◽  
Electron Energy ◽  
Electron Energy Loss Spectroscopy ◽  
Oxidation States ◽  
Fe Oxidation ◽  
Electron Energy Loss

Investigation of the oxidation states of Cu additive in colored borosilicate glasses by electron energy loss spectroscopy

2014 ◽  
Vol 116 (22) ◽  
pp. 223707 ◽  
Author(s):  
Guang Yang ◽  
Shaodong Cheng ◽  
Chao Li ◽  
Jiasong Zhong ◽  
Chuansheng Ma ◽  
...  
Keyword(s):  
Energy Loss ◽  
Electron Energy ◽  
Electron Energy Loss Spectroscopy ◽  
Oxidation States ◽  
Borosilicate Glasses ◽  
Cu Additive ◽  
Electron Energy Loss

Probing battery chemistry with liquid cell electron energy loss spectroscopy

2015 ◽  
Vol 51 (91) ◽  
pp. 16377-16380 ◽  
Author(s):  
Raymond R. Unocic ◽  
Loïc Baggetto ◽  
Gabriel M. Veith ◽  
Jeffery A. Aguiar ◽  
Kinga A. Unocic ◽  
...  
Keyword(s):  
Energy Loss ◽  
Electron Energy ◽  
Electron Energy Loss Spectroscopy ◽  
Oxidation States ◽  
Liquid Cell ◽  
Electron Energy Loss

We demonstrate the ability to apply electron energy loss spectroscopy (EELS) to follow the chemistry and oxidation states of LiMn2O4 and Li4Ti5O12 battery electrodes within a battery solvent.

A Study of [Cr-O6]-based rutile analogues by means of EELS

2008 ◽  
Vol 1148 ◽  
Author(s):  
Angel M. Arevalo-Lopez ◽  
Elizabeth Castillo-Martinez ◽  
Miguel Ángel Alario-Franco
Keyword(s):  
Energy Loss ◽  
Linear Relationship ◽  
Electron Energy ◽  
Oxidation State ◽  
Electron Energy Loss Spectroscopy ◽  
Oxidation States ◽  
Formal Oxidation State ◽  
Electron Energy Loss

AbstractWe present in here the study by means of electron energy loss spectroscopy (EELS) of several rutile based oxides, having in common the presence of octahedrally oxygen coordinated chromium, [Cr-O6], in three different formal oxidation states: Cr4+ in CrO2, a regular rutile; Cr3+ in CrOOH, a H bonded orthorrombic distorted rutile and in CrTaO4, a metal disordered rutile and Cr2+ in CrTa2O6 an ordered trirutile structure. A linear relationship is observed between the formal oxidation state of chromium in all these rutile oxides and the separation between the Cr-L2,3 and O-K energy loss peaks.

Mn Oxidation States in Bax CsyMnzTi8-zO16

2004 ◽  
Vol 824 ◽  
Author(s):  
M.L. Carter ◽  
E.R. Vance ◽  
D. R. G. Mitchell ◽  
Z. Zhang
Keyword(s):  
Energy Loss ◽  
Absorption Spectra ◽  
Electron Energy ◽  
Oxidation State ◽  
Electron Energy Loss Spectroscopy ◽  
Photoelectron Spectroscopy ◽  
Oxidation States ◽  
X Ray ◽  
Electron Energy Loss ◽  
X Ray Absorption

AbstractTwo Bax CsyMnzTi8-zO16 hollandite samples, containing excess rutile, have been prepared, targeting the Mn valence as 3+ by sintering at 1300oC in air (z = 2x +y) and as 2+ (z = x + y/2) in argon. SEM showed the sample sintered in air to contain major hollandite and minor Mn titanate and rutile. The sample sintered in argon contain major hollandite, and minor Ba titanate and rutile. X-ray absorption near edge spectroscopy (XANES), electron energy loss spectroscopy (EELS) and X-ray photoelectron spectroscopy (XPS) were used to determine the oxidation state of the Mn in the samples. Transmission manganese K-edge X-ray absorption spectra of the samples were similar but the precise ratio of oxidation states could not be calculated from these spectra.

scholarly journals Determining oxidation states of transition metals in molten salt corrosion using electron energy loss spectroscopy

2021 ◽  
Vol 197 ◽  
pp. 113790
Author(s):  
Kaustubh Bawane ◽  
Panayotis Manganaris ◽  
Yachun Wang ◽  
Jagadeesh Sure ◽  
Arthur Ronne ◽  
...  
Keyword(s):  
Transition Metals ◽  
Energy Loss ◽  
Molten Salt ◽  
Electron Energy ◽  
Electron Energy Loss Spectroscopy ◽  
Oxidation States ◽  
Salt Corrosion ◽  
Electron Energy Loss

Data Acquisition and Handling Unit for a Quantitative Use of Electron Energy Loss Spectroscopy

1977 ◽  
Vol 35 ◽  
pp. 232-233 ◽  
Author(s):  
P. Trebbia ◽  
P. Ballongue ◽  
C. Colliex
Keyword(s):  
Electron Microscope ◽  
Energy Loss ◽  
Electron Energy ◽  
Electron Energy Loss Spectroscopy ◽  
Single Channel ◽  
Detection System ◽  
Surface Barrier ◽  
Solid State Detector ◽  
Electrostatic Mirror ◽  
Electron Energy Loss

An effective use of electron energy loss spectroscopy for chemical characterization of selected areas in the electron microscope can only be achieved with the development of quantitative measurements capabilities.The experimental assembly, which is sketched in Fig.l, has therefore been carried out. It comprises four main elements.The analytical transmission electron microscope is a conventional microscope fitted with a Castaing and Henry dispersive unit (magnetic prism and electrostatic mirror). Recent modifications include the improvement of the vacuum in the specimen chamber (below 10-6 torr) and the adaptation of a new electrostatic mirror.The detection system, similar to the one described by Hermann et al (1), is located in a separate chamber below the fluorescent screen which visualizes the energy loss spectrum. Variable apertures select the electrons, which have lost an energy AE within an energy window smaller than 1 eV, in front of a surface barrier solid state detector RTC BPY 52 100 S.Q. The saw tooth signal delivered by a charge sensitive preamplifier (decay time of 5.10-5 S) is amplified, shaped into a gaussian profile through an active filter and counted by a single channel analyser.

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