scholarly journals High quality x-ray absorption spectroscopy measurements with long energy range at high pressure using diamond anvil cell

2009 ◽  
Vol 80 (7) ◽  
pp. 073908 ◽  
Author(s):  
Xinguo Hong ◽  
Matthew Newville ◽  
Vitali B. Prakapenka ◽  
Mark L. Rivers ◽  
Stephen R. Sutton
Author(s):  
Michael Pravica ◽  
Roman Chernikov ◽  
Kevin Ayala Pineda ◽  
Jianbao Zhao ◽  
Petrika Cifligu ◽  
...  

We examined the high pressure behavior of stannous oxalate via Raman and x-ray absorption spectroscopy (XAS) inside a diamond anvil cell. Phase transitions were observed to occur near 2.6 and...


2014 ◽  
Vol 43 (25) ◽  
pp. 9647-9654 ◽  
Author(s):  
K. Woodhead ◽  
S. Pascarelli ◽  
A. L. Hector ◽  
R. Briggs ◽  
N. Alderman ◽  
...  

The high pressure behavior of TaON was studied using a combination of Raman scattering, synchrotron X-ray diffraction, and X-ray absorption spectroscopy in diamond anvil cells to 70 GPa at ambient temperature to reveal evidence for a new structural transformation near 30 GPa.


Author(s):  
Jingming Shi ◽  
Emiliano Fonda ◽  
Silvana Botti ◽  
Miguel A. L. Marques ◽  
Toru Shinmei ◽  
...  

Metallization and dissociation are key transformations in diatomic molecules at high densities particularly significant for modeling giant planets. Using X-ray absorption spectroscopy and atomistic modeling, we demonstrate that in halogens,...


2001 ◽  
Vol 15 (18) ◽  
pp. 2491-2497 ◽  
Author(s):  
J. L. ZHU ◽  
L. C. CHEN ◽  
R. C. YU ◽  
F. Y. LI ◽  
J. LIU ◽  
...  

In situ high pressure energy dispersive X-ray diffraction measurements on layered perovskite-like manganate Ca 3 Mn 2 O 7 under pressures up to 35 GPa have been performed by using diamond anvil cell with synchrotron radiation. The results show that the structure of layered perovskite-like manganate Ca 3 Mn 2 O 7 is unstable under pressure due to the easy compression of NaCl-type blocks. The structure of Ca 3 Mn 2 O 7 underwent two phase transitions under pressures in the range of 0~35 GPa. One was at about 1.3 GPa with the crystal structure changing from tetragonal to orthorhombic. The other was at about 9.5 GPa with the crystal structure changing from orthorhombic back to another tetragonal.


1998 ◽  
Vol 5 (3) ◽  
pp. 989-991 ◽  
Author(s):  
Andrei Rogalev ◽  
Vincent Gotte ◽  
Jose´ Goulon ◽  
Christophe Gauthier ◽  
Joel Chavanne ◽  
...  

The first experimental applications of the undulator gap-scan technique in X-ray absorption spectroscopy are reported. The key advantage of this method is that during EXAFS scans the undulator is permanently tuned to the maximum of its emission peak in order to maximize the photon statistics. In X-MCD or spin-polarized EXAFS studies with a helical undulator of the Helios type, the polarization rate can also be kept almost constant over a wide energy range.


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