Observation of pressure-induced electron transfer in SnC2O4

2021 ◽  
Author(s):  
Michael Pravica ◽  
Roman Chernikov ◽  
Kevin Ayala Pineda ◽  
Jianbao Zhao ◽  
Petrika Cifligu ◽  
...  
Keyword(s):  
High Pressure ◽  
Electron Transfer ◽  
Phase Transitions ◽  
Absorption Spectroscopy ◽  
Diamond Anvil Cell ◽  
X Ray ◽  
Pressure Behavior ◽  
Diamond Anvil ◽  
X Ray Absorption

We examined the high pressure behavior of stannous oxalate via Raman and x-ray absorption spectroscopy (XAS) inside a diamond anvil cell. Phase transitions were observed to occur near 2.6 and...

scholarly journals High pressure polymorphism of β-TaON

2014 ◽  
Vol 43 (25) ◽  
pp. 9647-9654 ◽  
Author(s):  
K. Woodhead ◽  
S. Pascarelli ◽  
A. L. Hector ◽  
R. Briggs ◽  
N. Alderman ◽  
...  
Keyword(s):  
High Pressure ◽  
Raman Scattering ◽  
Ambient Temperature ◽  
Structural Transformation ◽  
Absorption Spectroscopy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Pressure Behavior ◽  
Diamond Anvil ◽  
X Ray Absorption

The high pressure behavior of TaON was studied using a combination of Raman scattering, synchrotron X-ray diffraction, and X-ray absorption spectroscopy in diamond anvil cells to 70 GPa at ambient temperature to reveal evidence for a new structural transformation near 30 GPa.

scholarly journals High quality x-ray absorption spectroscopy measurements with long energy range at high pressure using diamond anvil cell

2009 ◽  
Vol 80 (7) ◽  
pp. 073908 ◽  
Author(s):  
Xinguo Hong ◽  
Matthew Newville ◽  
Vitali B. Prakapenka ◽  
Mark L. Rivers ◽  
Stephen R. Sutton
Keyword(s):  
High Pressure ◽  
Energy Range ◽  
Absorption Spectroscopy ◽  
Diamond Anvil Cell ◽  
High Quality ◽  
X Ray ◽  
Diamond Anvil ◽  
X Ray Absorption

Phase transitions of CdS microcrystals under high pressure

1998 ◽  
Vol 5 (3) ◽  
pp. 1016-1019
Author(s):  
T. Nanba ◽  
M. Muneyasu ◽  
N. Hiraoka ◽  
S. Kaga ◽  
G. P. Williams ◽  
...  
Keyword(s):  
Surface Tension ◽  
High Pressure ◽  
Phase Transitions ◽  
Synchrotron Radiation ◽  
Lattice Dynamics ◽  
Diamond Anvil Cell ◽  
Lattice Stability ◽  
X Ray ◽  
Transition Pressure ◽  
Diamond Anvil

The experiment under high pressure using a diamond anvil cell (DAC) requires the utilization of synchrotron radiation. High-pressure experiments were performed using a DAC on CdS microcrystals, both in the far-IR and in the X-ray regions, in order to study the lattice dynamics and lattice stability concerned with the phase transitions. From these experiments, experimental evidence is presented indicating that a CdS microcrystal of smaller diameter shows a higher transition pressure for lattice transformation under pressure. The origin of such an increase in the transition pressure in the microcrystals is discussed in relation to the surface tension.

Halogens molecular modifications with high pressure: the case of iodine

2021 ◽  
Author(s):  
Jingming Shi ◽  
Emiliano Fonda ◽  
Silvana Botti ◽  
Miguel A. L. Marques ◽  
Toru Shinmei ◽  
...  
Keyword(s):  
High Pressure ◽  
Absorption Spectroscopy ◽  
Diatomic Molecules ◽  
Giant Planets ◽  
Atomistic Modeling ◽  
X Ray ◽  
X Ray Absorption

Metallization and dissociation are key transformations in diatomic molecules at high densities particularly significant for modeling giant planets. Using X-ray absorption spectroscopy and atomistic modeling, we demonstrate that in halogens,...

PHASE TRANSITION IN LAYERED PEROVSKITE LIKE MANGANATE Ca3Mn2O7 UNDER HIGH PRESSURE

2001 ◽  
Vol 15 (18) ◽  
pp. 2491-2497 ◽  
Author(s):  
J. L. ZHU ◽  
L. C. CHEN ◽  
R. C. YU ◽  
F. Y. LI ◽  
J. LIU ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Diamond Anvil Cell ◽  
The Other ◽  
Layered Perovskite ◽  
X Ray Diffraction ◽  
Two Phase ◽  
X Ray ◽  
Diamond Anvil

In situ high pressure energy dispersive X-ray diffraction measurements on layered perovskite-like manganate Ca 3 Mn 2 O 7 under pressures up to 35 GPa have been performed by using diamond anvil cell with synchrotron radiation. The results show that the structure of layered perovskite-like manganate Ca 3 Mn 2 O 7 is unstable under pressure due to the easy compression of NaCl-type blocks. The structure of Ca 3 Mn 2 O 7 underwent two phase transitions under pressures in the range of 0~35 GPa. One was at about 1.3 GPa with the crystal structure changing from tetragonal to orthorhombic. The other was at about 9.5 GPa with the crystal structure changing from orthorhombic back to another tetragonal.

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