Intramolecular energy transfer between the triplet of ancillary ligand and the metal to ligand charge transfer state existed in heterocyclometalated iridium (III) complexes

2009 ◽  
Vol 94 (16) ◽  
pp. 163303 ◽  
Author(s):  
Liangliang Han ◽  
Dongfang Yang ◽  
Wenlian Li ◽  
Bei Chu ◽  
Yiren Chen ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Charge Transfer ◽  
Charge Transfer State ◽  
Intramolecular Energy Transfer ◽  
Ancillary Ligand ◽  
Ligand Charge Transfer ◽  
Transfer State

The Role of the Ligand-to-Metal Charge-Transfer State in the Dipivaloylmethanate-Lanthanide Intramolecular Energy Transfer Process

2015 ◽  
Vol 2015 (18) ◽  
pp. 3019-3027 ◽  
Author(s):  
Yolanda C. Miranda ◽  
Leide L. A. L. Pereira ◽  
José H. P. Barbosa ◽  
Hermi F. Brito ◽  
Maria C. F. C. Felinto ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Charge Transfer ◽  
Transfer Process ◽  
Energy Transfer Process ◽  
Charge Transfer State ◽  
Intramolecular Energy Transfer ◽  
Metal Charge ◽  
Metal Charge Transfer ◽  
Transfer State

Tuning of the lowest excited states in mixed ruthenium(ii) polypyridyl complexes having RuN6 cores by the conformation of the ancillary ligand. Emission from a 3ligand-to-ligand-charge-transfer state

2016 ◽  
Vol 40 (6) ◽  
pp. 5002-5009 ◽  
Author(s):  
Nirmal K. Shee ◽  
Michael G. B. Drew ◽  
Dipankar Datta
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Excited States ◽  
Small Difference ◽  
Charge Transfer State ◽  
Ancillary Ligand ◽  
Polypyridyl Complexes ◽  
Ligand Charge Transfer ◽  
Transfer State

A small difference in the conformation of an ancillary ligand L determines the lowest excited state in [Ru(bpy)2L]2+ and [Ru(phen)2L]2+.

Detailed Description of the Metal-to-Ligand Charge-Transfer State in Monoterpyridine IrIII Complexes

2009 ◽  
Vol 2009 (14) ◽  
pp. 2067-2073 ◽  
Author(s):  
Naokazu Yoshikawa ◽  
Shinichi Yamabe ◽  
Nobuko Kanehisa ◽  
Tsuyoshi Inoue ◽  
Hiroshi Takashima ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer State ◽  
Ligand Charge Transfer ◽  
Transfer State

Photooxidation of Dicyanoaurate(I) Induced by Metal-to-Ligand Charge Transfer Excitation

1998 ◽  
Vol 53 (8) ◽  
pp. 853-855 ◽  
Author(s):  
Horst Kunkely ◽  
Arad Vogler
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Charge Transfer ◽  
Charge Transfer State ◽  
State Electron ◽  
Ligand Charge Transfer ◽  
Charge Transfer Excitation ◽  
Transfer State

Abstract The irradiation of [Au(CN)2]- in oxygen-saturated acetonitrile leads to photooxidation of Au(I). In the presence of additional chloride [Au(CN)2CL2]- is formed with φ= 0.5 x 10-4 at λirr = 254 nm. It is assumed that [Au(CN)2]- in its metal-to-ligand charge transfer state undergoes an excited state electron transfer to oxygen in the primary photochemical step.

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