Photochemical activation of carbon dioxide. Transient absorbance kinetic studies of the addition of carbon dioxide to a metal-to-bridging ligand charge-transfer state of a binuclear nickel(0) complex

1988 ◽  
Vol 110 (20) ◽  
pp. 6904-6906 ◽  
Author(s):  
Frederick R. Lemke ◽  
Dru L. DeLaet ◽  
Jiali. Gao ◽  
Clifford P. Kubiak
Keyword(s):  
Carbon Dioxide ◽  
Charge Transfer ◽  
Kinetic Studies ◽  
Charge Transfer State ◽  
Bridging Ligand ◽  
Ligand Charge Transfer ◽  
Transient Absorbance ◽  
Transfer State ◽  
Photochemical Activation

Detailed Description of the Metal-to-Ligand Charge-Transfer State in Monoterpyridine IrIII Complexes

2009 ◽  
Vol 2009 (14) ◽  
pp. 2067-2073 ◽  
Author(s):  
Naokazu Yoshikawa ◽  
Shinichi Yamabe ◽  
Nobuko Kanehisa ◽  
Tsuyoshi Inoue ◽  
Hiroshi Takashima ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer State ◽  
Ligand Charge Transfer ◽  
Transfer State

Photooxidation of Dicyanoaurate(I) Induced by Metal-to-Ligand Charge Transfer Excitation

1998 ◽  
Vol 53 (8) ◽  
pp. 853-855 ◽  
Author(s):  
Horst Kunkely ◽  
Arad Vogler
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Charge Transfer ◽  
Charge Transfer State ◽  
State Electron ◽  
Ligand Charge Transfer ◽  
Charge Transfer Excitation ◽  
Transfer State

Abstract The irradiation of [Au(CN)2]- in oxygen-saturated acetonitrile leads to photooxidation of Au(I). In the presence of additional chloride [Au(CN)2CL2]- is formed with φ= 0.5 x 10-4 at λirr = 254 nm. It is assumed that [Au(CN)2]- in its metal-to-ligand charge transfer state undergoes an excited state electron transfer to oxygen in the primary photochemical step.

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