Laser-Induced Dynamical Chirality and Intramolecular Energy Flow in the CH Chromophore

2007 ◽  
Author(s):  
Ioannis Thanopulos ◽  
George Maroulis ◽  
Theodore E. Simos
Keyword(s):  
Energy Flow ◽  
Intramolecular Energy Flow

Large intramolecular energy flow in vibrational overtone spectra of cyclohexene-3,3,6,6-d4

1993 ◽  
Vol 97 (23) ◽  
pp. 6134-6141 ◽  
Author(s):  
L. Lespade ◽  
S. Rodin ◽  
D. Cavagnat ◽  
S. Abbate
Keyword(s):  
Energy Flow ◽  
Vibrational Overtone ◽  
Intramolecular Energy Flow

Classical dynamics study of intramolecular energy flow in benzene

1986 ◽  
Vol 85 (4) ◽  
pp. 1848-1853 ◽  
Author(s):  
Karen L. Bintz ◽  
Donald L. Thompson ◽  
John W. Brady
Keyword(s):  
Energy Flow ◽  
Classical Dynamics ◽  
Intramolecular Energy Flow

Restricted Intramolecular Energy Flow in Large Molecules. Heterogeneous and Enzyme Catalysis

1997 ◽  
Vol 62 (8) ◽  
pp. 1150-1158 ◽  
Author(s):  
Milan Šolc
Keyword(s):  
Energy Flow ◽  
Enzyme Catalysis ◽  
Reaction Rate ◽  
Vibrational Energy ◽  
Heavy Atom ◽  
Energy Localization ◽  
Large Molecules ◽  
Substrate Complex ◽  
Enzyme Substrate ◽  
Intramolecular Energy Flow

The free intramolecular energy flow can be restricted by the presence of a heavy atom in the molecule. As a result of this restriction, adsorbed molecules bonded on the metal surface and/or substrate molecules in the enzyme-substrate complex with a metal atom near the binding site can have a higher vibrational energy than the surroundings. The reaction rate is then enhanced by this energy localization.

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