Effect of Co doping on the static dielectric constant of ZnO nanoparticles

2007 ◽  
Vol 101 (12) ◽  
pp. 124911 ◽  
Author(s):  
C. K. Ghosh ◽  
K. K. Chattopadhyay ◽  
M. K. Mitra
RSC Advances ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 5179-5181
Author(s):  
Sayantan Mondal ◽  
Biman Bagchi

Neglects of inherent anisotropy and distinct dielectric boundaries may lead to completely erroneous results. We demonstrate that such mistakes can give rise to gross underestimation of the static dielectric constant of cylindrically nanoconfined water.


1964 ◽  
Vol 19 (9) ◽  
pp. 1070-1075
Author(s):  
H. Vogel ◽  
H. Bässler

The activation energy of the d. c. conductance of organic liquids lies between 0.04 and 0.45 eV in the lower region of temperature of their liquid state. A comparison of these values with the static dielectric constant shows, that the activation energy may be regarded as a pure COULOMB energy: E2 = e2/2 ε r . The characteristic distance r has the approximate value of 8.5 Å for hydrocarbons. It decreases for halogen- and nitro-derivates. Formerly it was found that the conductivity of mixtures obeys the law σM = σAC · σB1-C. This can easily be explained assuming εM = c εA + (1 — c) εB. In the case of rather different ε values or of homologuous compounds forming complexes, σ increases. This is identical with a kink in the log σ (c) -curve.


2021 ◽  
pp. 089270572110386
Author(s):  
Ali F Al-Shawabkeh ◽  
Ziad M Elimat ◽  
Khaleel N Abushgair

The goal of this study was to investigate the optical properties of the prepared polyvinyl chloride (PVC)/zinc oxide (ZnO) nanocomposite films. The PVC/ZnO nanocomposite films consist of the addition of different concentrations with both non-annealed ZnO nanoparticles and ZnO nanoparticles annealed at temperature of 700°C. The PVC/ZnO nanocomposite films by weight concentrations of (0 wt.%, 2.5 wt.%, 5 wt.% and 10 wt.%) have been prepared by the casting method. The optical absorbance and transmittance values of the composites films were measured in the wavelength range between (250 to 1100 nm) at room temperature by using the UV-1800 Shimadzu spectrophotometer. The optical properties (absorption coefficient, dielectric constant, refractive index, and optical conductivity) have been investigated by the ultraviolet (UV) spectrophotometer. The optical parameters (direct optical energy gap, excitation energy for electronic transitions, the dispersion energy, static refractive index, static dielectric constant, optical oscillator strengths, the moments of optical spectrum, linear optical susceptibility, third-order nonlinear optical susceptibility, nonlinear refractive index, high-frequency dielectric constant, the carrier concentration to the effective mass ratio, the long wavelength refractive index and the plasma frequency) were calculated. The results showed that the optical properties behavior of the PVC/ZnO nanocomposite films was found to be dependent on the ZnO concentration, and photon wavelength. In addition, the results of the study show that the optical parameters can be influenced by alter the concentration of the nonannealed and annealed a ZnO nanoparticle in the PVC polymer matrix.


2019 ◽  
Vol 97 (3) ◽  
pp. 227-232 ◽  
Author(s):  
Ye Zhao ◽  
Fan Tong ◽  
Mao Hua Wang

Pure and cobalt-doped ZnO nanoparticles (2.5, 5, 7.5, and 10 atom % Co) are synthesized by sol–gel method. The as-synthesized nanoparticles are characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and field emission scanning electron microscopy (FE-SEM) analysis. The nanoparticles of 0, 2.5, and 5 atom % Co-doped ZnO exhibited hexagonal wurtzite structure and have no other phases. Moreover, the (101) diffraction peaks position of Co-doped ZnO shift toward a smaller value of diffraction angle compared with pure ZnO powders. The results confirm that Co ions were well incorporated into ZnO crystal lattice. Simultaneously, Co doping also inhibited the growth of particles, and the crystallite size decreased from 43.11 nm to 36.63 nm with the increase in doping concentration from 0 to 10 atom %. The values of the optical band gap of all Co-doped ZnO nanoparticles gradually decreased from 3.09 eV to 2.66 eV with increasing Co content. Particular, the dielectric constant of all Co-doped ZnO ceramics gradually increased from 1.62 × 103 to 20.52 × 103, and the dielectric loss decreased from 2.36 to 1.28 when Co content increased from 0 to 10 atom %.


2016 ◽  
Vol 697 ◽  
pp. 271-274
Author(s):  
Gui Min Jiang ◽  
Ji Kang Yan ◽  
Gang Yang ◽  
Zhi Cao Duan ◽  
Kun Yong Kang ◽  
...  

The present study investigated the effect of the sintering temperature and (Y2O3, V2O5) co-doping on the performance of TiO2 varistor ceramic which has lower varistor voltage and high nonlinear coefficient. The results showed that the TiO2-based varistor ceramic which doped with 0.35% mol and 0.25% mol of Y2O3 and V2O5 has good comprehensive electrical performance and excellent dielectric constant sintered at 1200°C. Its varistor voltage V1mA is 38.1V, nonlinear coefficient is 4.6.


1982 ◽  
Vol 43 (7) ◽  
pp. 507-510 ◽  
Author(s):  
A. Jànossy ◽  
K. Holczer ◽  
P.L. Hsieh ◽  
C.M. Jackson ◽  
A. Zettl

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