Geometries and excited-state dynamics of van der Waals dimers and higher clusters of 1-cyanonaphthalene

2005 ◽  
Vol 123 (24) ◽  
pp. 244306 ◽  
Author(s):  
Takashige Fujiwara ◽  
Ricardo Campos Ramos ◽  
Marek Z. Zgierski ◽  
Edward C. Lim
1987 ◽  
Vol 91 (14) ◽  
pp. 3750-3758 ◽  
Author(s):  
James W. Hager ◽  
Gary W. Leach ◽  
David R. Demmer ◽  
Stephen C. Wallace

1994 ◽  
Vol 14 (1-3) ◽  
pp. 45-59 ◽  
Author(s):  
Shane M. Ohline ◽  
Joann Romascan ◽  
Peter M. Felker

We report the results of rotational coherence spectroscopy on tolane, tolane–Ar, and tolane–N2. The results on tolane are consistent with a planar geometry for the species. They also provide information about the symmetries of excited vibronic states in the species. The results on the van der Waals complexes provide significant experimental constraints on where the small species bind to tolane. In addition, we report the observation of a rapid excited-state decay process in the complexes and discuss the possible nature of this process.


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