The Free Exciton Binding Energy in a Strained GaN0.02As0.98 Layer

Author(s):  
R. Kudrawiec
MRS Bulletin ◽  
1998 ◽  
Vol 23 (4) ◽  
pp. 33-38 ◽  
Author(s):  
Leonid Tsybeskov

Light emission in silicon has been intensively investigated since the 1950s when crystalline silicon (c-Si) was recognized as the dominant material in microelectronics. Silicon is an indirect-bandgap semiconductor and momentum conservation requires phonon assistance in radiative electron-hole recombination (Figure 1a, top left). Because phonons carry a momentum and an energy, the typical signature of phonon-assisted recombination is several peaks in the photoluminescence (PL) spectra at low temperature. These PL peaks are called “phonon replicas.” High-purity c-Si PL is caused by free-exciton self-annihilation with the exciton binding energy of ~11 meV. The TO-phonon contribution in conservation processes is most significant, and the main PL peak (~1.1 eV) is shifted from the bandgap value (~1.17 eV) by ~70 meV—that is, the exciton binding energy plus TO-phonon energy (Figure 1a).


2001 ◽  
Vol 353-356 ◽  
pp. 405-408 ◽  
Author(s):  
Ivan G. Ivanov ◽  
T. Egilsson ◽  
Jie Zhang ◽  
Alexsandre Ellison ◽  
Erik Janzén

2002 ◽  
Vol 389-393 ◽  
pp. 613-616 ◽  
Author(s):  
Ivan G. Ivanov ◽  
Jie Zhang ◽  
L. Storasta ◽  
Erik Janzén

2013 ◽  
Vol 103 (25) ◽  
pp. 251908 ◽  
Author(s):  
M. Wełna ◽  
R. Kudrawiec ◽  
A. Kaminska ◽  
A. Kozanecki ◽  
B. Laumer ◽  
...  

1995 ◽  
Vol 189 (2) ◽  
pp. K45-K47
Author(s):  
W. Z. Shen ◽  
W. G. Tang ◽  
S. C. Shen

1996 ◽  
Vol 449 ◽  
Author(s):  
B. J. Skromme ◽  
H. Zhao ◽  
B. Goldenberg ◽  
H. S. Kong ◽  
M. T. Leonard ◽  
...  

ABSTRACTWe report several new aspects of the excitonic properties of heteroepitaxial GaN grown on sapphire or 6H-SiC. In particular, we observed the n = 2 free exciton associated with both A and B excitons (which are distinct from the n = 1 C exciton) using reflectance and 1.7 K photoluminescence. We also studied the behavior of the n = 2 A-exciton using magnetoluminescence in fields up to 12 T. The large diamagnetic shift and splitting positively confirm the identification, yielding an exciton binding energy of about 26.4 meV. Several previous identifications of the n = 2 free exciton yielding a smaller exciton binding energy are probably in error, based on our results. We have also detected the two-electron replica of the neutral donor-bound exciton for the first time in GaN and observed its splitting pattern in magnetic fields up to 12 T. This feature is 22 meV below the principal neutral donor-bound exciton peak, independently of strain shifts in the overall spectrum. It yields a precise donor binding energy of 29 meV for the shallow residual donor in material grown by metalorganic chemical vapor deposition and gas-source molecular beam epitaxy, considerably smaller than that of the residual donor reported earlier in hydride vapor phase epitaxial material (about 35.5 meV).


Sign in / Sign up

Export Citation Format

Share Document