scholarly journals The reaction rate for dissociative adsorption of N2 on stepped Ru(0001): Six-dimensional quantum calculations

2005 ◽  
Vol 122 (23) ◽  
pp. 234702 ◽  
Author(s):  
Rob van Harrevelt ◽  
Karoliina Honkala ◽  
Jens K. Nørskov ◽  
Uwe Manthe
Keyword(s):  
Reaction Rate ◽  
Dissociative Adsorption ◽  
Quantum Calculations ◽  
Adsorption Of N2

Full dimensional quantum calculations of the CH[sub 4]+H→CH[sub 3]+H[sub 2] reaction rate

2000 ◽  
Vol 113 (13) ◽  
pp. 5115 ◽  
Author(s):  
Fermı́n Huarte-Larrañaga ◽  
Uwe Manthe
Keyword(s):  
Reaction Rate ◽  
Quantum Calculations

Dissociative adsorption of N2 on the W(100) surface

2004 ◽  
Vol 556 (2-3) ◽  
pp. 129-144 ◽  
Author(s):  
G Volpilhac ◽  
A Salin
Keyword(s):  
Dissociative Adsorption ◽  
Adsorption Of N2

The influence of surface metal composition of FeCr alloys on the dissociative adsorption of N2

1988 ◽  
Vol 193 (3) ◽  
pp. 336-352 ◽  
Author(s):  
P.A. Dowben ◽  
A. Miller ◽  
H.-J. Ruppender ◽  
M. Grunze
Keyword(s):  
Dissociative Adsorption ◽  
Metal Composition ◽  
Surface Metal ◽  
Adsorption Of N2

Chemistry of Transition Metals. V. Further Studies on the Mechanism of Reaction of n-Alkyl Chlorides with Metals of the First Transition Period

1975 ◽  
Vol 53 (17) ◽  
pp. 2619-2623 ◽  
Author(s):  
Robert W. Egan ◽  
John F. Harrod
Keyword(s):  
Transition Metals ◽  
Pressure Range ◽  
Reaction Rate ◽  
Transition Period ◽  
Halogen Bond ◽  
Dissociative Adsorption ◽  
Rate Law ◽  
Order Rate ◽  
Mechanism Of Reaction ◽  
Rate Of Reaction

The rate of reaction of n-propyl chloride on polycrystalline evaporated titanium films has been shown to follow a strictly half-order rate law in the pressure range 0.1–0.01 Torr at 220 °C. The reaction rate was not influenced by the product propene. Experiments using a mixture of 1-bromopropane and l-chloropropane-1-d1 gave no indication of halogen interchange on either titanium or chromium, thus excluding rapid, reversible dissociative adsorption of the carbon–halogen bond as an explanation of the half-order rate law.

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