Electronic spectroscopy of toluene–rare-gas clusters: The external heavy atom effect and vibrational predissociation

2005 ◽  
Vol 122 (19) ◽  
pp. 194315 ◽  
Author(s):  
Richard J. Doyle ◽  
Emily S. J. Love ◽  
Raffaello Da Campo ◽  
Stuart R. Mackenzie
Keyword(s):  
Heavy Atom ◽  
Electronic Spectroscopy ◽  
Rare Gas ◽  
Heavy Atom Effect ◽  
Vibrational Predissociation ◽  
Gas Clusters ◽  
Atom Effect ◽  
Rare Gas Clusters

Achieving high singlet-oxygen generation by applying the heavy-atom effect to thermally activated delayed fluorescent materials

2021 ◽  
Author(s):  
Ya-Fang Xiao ◽  
Jia-Xiong Chen ◽  
Wen-Cheng Chen ◽  
Xiuli Zheng ◽  
Chen Cao ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Heavy Atom ◽  
Synergetic Effect ◽  
Heavy Atom Effect ◽  
Oxygen Generation ◽  
Thermally Activated ◽  
Singlet Oxygen Generation ◽  
Fluorescent Materials ◽  
Atom Effect

Applying the heavy-atom effect to TADF photosensitizers achieves ultra-high 1O2 generation (ФΔ = 0.91) by the synergetic effect of small ΔEST and considerable SOC.

Enhancement of Reverse Intersystem Crossing in Charge‐Transfer Molecule through Internal Heavy Atom Effect

2021 ◽  
pp. 2104646
Author(s):  
Hyung Suk Kim ◽  
Ja Yeon Lee ◽  
Seongjun Shin ◽  
Wonkyo Jeong ◽  
Sang Hoon Lee ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Heavy Atom ◽  
Intersystem Crossing ◽  
Heavy Atom Effect ◽  
Atom Effect
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