The principles of infrared-x-ray pump-probe spectroscopy. Applications on proton transfer in core-ionized water dimers

2005 ◽  
Vol 122 (9) ◽  
pp. 094319 ◽  
Author(s):  
V. C. Felicíssimo ◽  
F. F. Guimarães ◽  
F. Gel’mukhanov ◽  
A. Cesar ◽  
H. Ågren
Keyword(s):  
Proton Transfer ◽  
Pump Probe ◽  
X Ray ◽  
Probe Spectroscopy ◽  
Water Dimers

Proton Transfer Mediated by the Vibronic Coupling in Oxygen Core Ionized States of Glyoxalmonoxime Studied by Infrared−X-ray Pump−Probe Spectroscopy

2006 ◽  
Vol 110 (47) ◽  
pp. 12805-12813 ◽  
Author(s):  
V. C. Felicíssimo ◽  
F. F. Guimarães ◽  
A. Cesar ◽  
F. Gel'mukhanov ◽  
H. Ågren
Keyword(s):  
Proton Transfer ◽  
Vibronic Coupling ◽  
Pump Probe ◽  
X Ray ◽  
Probe Spectroscopy

Infrared–x-ray pump-probe spectroscopy of the NO molecule

2005 ◽  
Vol 72 (1) ◽  
Author(s):  
F. F. Guimarães ◽  
V. Kimberg ◽  
V. C. Felicíssimo ◽  
F. Gel’mukhanov ◽  
A. Cesar ◽  
...  
Keyword(s):  
Pump Probe ◽  
X Ray ◽  
Probe Spectroscopy

Quantum wave packet revivals in IR+X-ray pump–probe spectroscopy

2005 ◽  
Vol 405 (4-6) ◽  
pp. 398-403 ◽  
Author(s):  
F.F. Guimarães ◽  
F. Gel’mukhanov ◽  
A. Cesar ◽  
H. Ågren
Keyword(s):  
Wave Packet ◽  
Pump Probe ◽  
X Ray ◽  
Quantum Wave ◽  
Probe Spectroscopy

scholarly journals In depth characterization of Ge-Si core-shell nanowires using X-ray coherent diffraction and time resolved pump-probe spectroscopy

2019 ◽  
Vol 126 (20) ◽  
pp. 204304
Author(s):  
Sara Fernández ◽  
Cyril Jean ◽  
Eric Charron ◽  
Pascal Gentile ◽  
Marie-Ingrid Richard ◽  
...  
Keyword(s):  
Core Shell ◽  
Time Resolved ◽  
Pump Probe ◽  
X Ray ◽  
Probe Spectroscopy ◽  
Shell Nanowires

scholarly journals URSA-PQ: A Mobile and Flexible Pump-Probe Instrument for Gas Phase Samples at the FLASH Free Electron Laser

2020 ◽  
Vol 10 (21) ◽  
pp. 7882
Author(s):  
Jan Metje ◽  
Fabiano Lever ◽  
Dennis Mayer ◽  
Richard James Squibb ◽  
Matthew S. Robinson ◽  
...  
Keyword(s):  
Gas Phase ◽  
Time Resolution ◽  
Laser Pulses ◽  
Pump Probe ◽  
X Ray ◽  
Wide Range ◽  
Technical Features ◽  
Magnetic Bottle ◽  
Probe Spectroscopy ◽  
Different Origins

We present a highly flexible and portable instrument to perform pump-probe spectroscopy with an optical and an X-ray pulse in the gas phase. The so-called URSA-PQ (German for ‘Ultraschnelle Röntgenspektroskopie zur Abfrage der Photoenergiekonversion an Quantensystemen’, Engl. ‘ultrafast X-ray spectroscopy for probing photoenergy conversion in quantum systems’) instrument is equipped with a magnetic bottle electron spectrometer (MBES) and tools to characterize the spatial and temporal overlap of optical and X-ray laser pulses. Its adherence to the CAMP instrument dimensions allows for a wide range of sample sources as well as other spectrometers to be included in the setup. We present the main design and technical features of the instrument. The MBES performance was evaluated using Kr M4,5NN Auger lines using backfilled Kr gas, with an energy resolution ΔE/E ≅ 1/40 in the integrating operative mode. The time resolution of the setup at FLASH 2 FL 24 has been characterized with the help of an experiment on 2-thiouracil that is inserted via the instruments’ capillary oven. We find a time resolution of 190 fs using the molecular 2p photoline shift and attribute this to different origins in the UV-pump—the X-ray probe setup.

scholarly journals Probing spin–vibronic dynamics using femtosecond X-ray spectroscopy

2016 ◽  
Vol 194 ◽  
pp. 731-746 ◽  
Author(s):  
T. J. Penfold ◽  
M. Pápai ◽  
T. Rozgonyi ◽  
K. B. Møller ◽  
G. Vankó
Keyword(s):  
Excited State ◽  
Degrees Of Freedom ◽  
Free Electrons ◽  
Edge Structure ◽  
Pump Probe ◽  
X Ray ◽  
Wavepacket Dynamics ◽  
Methyl Imidazole ◽  
Probe Spectroscopy ◽  
X Ray Absorption

Ultrafast pump-probe spectroscopy within the X-ray regime is now possible owing to the development of X-ray Free Electrons Lasers (X-FELs) and is opening new opportunities for the direct probing of femtosecond evolution of the nuclei, the electronic and spin degrees of freedom. In this contribution we use wavepacket dynamics of the photoexcited decay of a new Fe(ii) complex, [Fe(bmip)2]2+ (bmip = 2,6-bis(3-methyl-imidazole-1-ylidine)pyridine), to simulate the experimental observables associated with femtosecond Fe K-edge X-ray Absorption Near-Edge Structure (XANES) and X-ray emission (XES) spectroscopy. We show how the evolution of the nuclear wavepacket is translated into the spectroscopic signal and the sensitivity of these approaches for following excited state dynamics.

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