Near-field optical beam-induced currents in CdTe∕CdS solar cells: Direct measurement of enhanced photoresponse at grain boundaries

2004 ◽  
Vol 85 (17) ◽  
pp. 3854-3856 ◽  
Author(s):  
S. Smith ◽  
P. Zhang ◽  
T. Gessert ◽  
A. Mascarenhas
2005 ◽  
Vol 865 ◽  
Author(s):  
S. Smith ◽  
R. Dhere ◽  
T. Gessert ◽  
P. Stradins ◽  
T. Wang ◽  
...  

AbstractGeneration, transport and collection of carriers in polycrystalline (PX) solar cells and their constituent materials are poorly understood, and significantly different than in their single-crystal counterparts. Recent theoretical and experimental results have put forth the expectation that grain boundaries in PX-solar cell materials such as CdTe and CuInGaSe2, either as-grown or after appropriate post-growth treatment, may have electronic properties which are advantageous to charge separation and solar cell operation[1-3]. However, a microscopic picture of the spatial variations in the optoelectronic properties of these materials is, for the most part, still lacking. The goal of the work reported here is to explore the optoelectronic and spectroscopic properties of grain-boundaries in these materials at the nanometer length-scale, via novel, high-resolution optical techniques. Towards this end, a significant enhancement in photo-response near grain boundaries in CdTe solar cells, consistent with models put forth in reference 2, was observed via near-field Optical Beam Induced Current (n-OBIC) [4]. A systematic μ-PL study of the effect of CdC12-treatment on recombination in CdTe/CdS solar cell structures of varying thickness directly examined the variation in optoelectronic properties at grain-boundaries in this material, revealing the grain-boundary and surface passivation effects of this important post-growth processing step. For comparison, we also studied the effects of SiNx post-growth treatment and annealing on the photo-response of PX-silicon solar cells using n-OBIC. These results and our most-recent n-OBIC measurements in CdTe and CuInGaSe2 solar cells are discussed.


1997 ◽  
Vol 472 ◽  
Author(s):  
A. A. McDaniel ◽  
J. W. P. Hsu

ABSTRACTPhotovoltage images of Cu(In,Ga)Se2 solar cells taken using near-field scanning optical microscopy (NSOM) show reduction of photoresponse along grain boundaries. Two factors might be responsible for this contrast. The first is that the topographic changes associated with the grains could cause the NSOM tip to move further from the sample, resulting in a reduction in photoresponse. The second possibility is that the contrast is due to real physical properties of the sample, e.g. higher recombination velocities near grain boundaries. We show convincing evidence that the major contribution to the contrast in the photovoltage images is due to the latter.


2018 ◽  
Vol 183 ◽  
pp. 34-40 ◽  
Author(s):  
Manoj Vishwakarma ◽  
Deepak Varandani ◽  
Christian Andres ◽  
Yaroslav E. Romanyuk ◽  
Stefan G. Haass ◽  
...  

Nano Energy ◽  
2021 ◽  
pp. 106388
Author(s):  
Mohammad Ismail Hossain ◽  
Md. Shahiduzzaman ◽  
Safayet Ahmed ◽  
Md. Rashedul Huqe ◽  
Wayesh Qarony ◽  
...  

1990 ◽  
Vol 12 (1-4) ◽  
pp. 381-388 ◽  
Author(s):  
Joachim Fritz ◽  
Rainer Lackmann

2002 ◽  
Vol 81 (8) ◽  
pp. 1503-1505 ◽  
Author(s):  
D. A. Lapshin ◽  
V. S. Letokhov ◽  
G. T. Shubeita ◽  
S. K. Sekatskii ◽  
G. Dietler

1986 ◽  
Vol 59 (7) ◽  
pp. 2571-2576 ◽  
Author(s):  
Ryuichi Shimokawa ◽  
Yutaka Hayashi

1969 ◽  
Vol 3 (9) ◽  
pp. 663-665 ◽  
Author(s):  
S.J. Bercovici ◽  
P. Niessen ◽  
J.J. Byerley

Solar Energy ◽  
2021 ◽  
Vol 224 ◽  
pp. 472-479
Author(s):  
Ronghong Zheng ◽  
Shuangshuang Zhao ◽  
Hua Zhang ◽  
Haoyue Li ◽  
Jia Zhuang ◽  
...  

2021 ◽  
Author(s):  
Giuk Jeong ◽  
Seunghwan Ji ◽  
Ji Woon Choi ◽  
Gihun Jung ◽  
Byungha Shin

Sb2Se3, a quasi-1D structured binary chalcogenide, has great potential as a solar cell light absorber owing to its anisotropic carrier transport and benign grain boundaries when the absorber layer is...


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