The Kinetics of the Homogeneous Thermal Decomposition of Ethyl Ether at Pressures up to Two Hundred Atmospheres

1934 ◽  
Vol 2 (8) ◽  
pp. 503-512 ◽  
Author(s):  
E. W. R. Steacie ◽  
Ernest Solomon
Keyword(s):  
Thermal Decomposition ◽  
Ethyl Ether ◽  
Kinetics Of

THE KINETICS OF THE THERMAL DECOMPOSITION OF VINYL ISOPROPYL ETHER

1953 ◽  
Vol 31 (4) ◽  
pp. 418-421 ◽  
Author(s):  
Arthur T. Blades
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Free Radical ◽  
Ethyl Ether ◽  
Close Agreement ◽  
Flow System ◽  
Isopropyl Ether ◽  
Radical Decomposition ◽  
A Minor ◽  
Kinetics Of

The thermal decomposition of vinyl isopropyl ether in the presence of toluene has been studied in a flow system in the temperature range 447–521 °C. In this range, the data indicate a purely intramolecular decomposition into propylene and acetaldehyde, the activation energy for the reaction being in close agreement with that found for the decomposition of vinyl ethyl ether. At 570 °C. a minor free radical decomposition of the ether becomes apparent. Some qualitative studies of the decomposition of vinyl isobutyl ether are also reported.

Kinetics of Thermal Decomposition of Lime Stone

1967 ◽  
Vol 53 (7) ◽  
pp. 740-743 ◽  
Author(s):  
Kiyoshi SAWAMURA ◽  
Kazuichi MIZOGUCHI ◽  
Tetsuro HANADA ◽  
Kunihiko MAKINO
Keyword(s):  
Thermal Decomposition ◽  
Kinetics Of Thermal Decomposition ◽  
Kinetics Of ◽  
Lime Stone

Thermal Decomposition Kinetics of Torrefied Oil Palm Empty Fruit Bunch Briquettes

2016 ◽  
Vol 10 (3) ◽  
pp. 325-328 ◽  
Author(s):  
Bemgba Nyakuma ◽  
◽  
Arshad Ahmad ◽  
Anwar Johari ◽  
Tuan Abdullah ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Oil Palm ◽  
Decomposition Kinetics ◽  
Thermal Decomposition Kinetics ◽  
Kinetic Properties ◽  
Tg Analysis ◽  
Empty Fruit Bunches ◽  
Thermal Lag ◽  
Profile Characteristics ◽  
Kinetics Of

The study is aimed at investigating the thermal behavior and decomposition kinetics of torrefied oil palm empty fruit bunches (OPEFB) briquettes using a thermogravimetric (TG) analysis and the Coats-Redfern model. The results revealed that thermal decomposition kinetics of OPEFB and torrefied OPEFB briquettes is significantly influenced by the severity of torrefaction temperature. Furthermore, the temperature profile characteristics; Tonset, Tpeak, and Tend increased consistently due to the thermal lag observed during TG analysis. In addition, the torrefied OPEFB briquettes were observed to possess superior thermal and kinetic properties over the untorrefied OPEFB briquettes. It can be inferred that torrefaction improves the fuel properties of pelletized OPEFB for potential utilization in bioenergy conversion systems.

Thermal Decomposition Kinetics of Glyphosate (GP) and its Metabolite Aminomethylphosphonic Acid (AMPA)

2019 ◽  
Author(s):  
Milad Narimani ◽  
Gabriel da Silva
Keyword(s):  
Thermal Decomposition ◽  
Reaction Rate ◽  
Decomposition Kinetics ◽  
Rate Theory ◽  
Thermal Decomposition Mechanism ◽  
Treatment Processes ◽  
Aminomethylphosphonic Acid ◽  
Reaction Rate Theory ◽  
Decomposition Chemistry ◽  
Kinetics Of

Glyphosate (GP) is a widely used herbicide worldwide, yet accumulation of GP and its main byproduct, aminomethylphosphonic acid (AMPA), in soil and water has raised concerns about its potential effects to human health. Thermal treatment processes are one option for decontaminating material containing GP and AMPA, yet the thermal decomposition chemistry of these compounds remains poorly understood. Here, we have revealed the thermal decomposition mechanism of GP and AMPA by applying computational chemistry and reaction rate theory methods. <br>

The effect of electrondonors on the polymerization kinetics of isoprene

1980 ◽  
Vol 45 (12) ◽  
pp. 3338-3346
Author(s):  
Miroslav Kašpar ◽  
Jiří Trekoval
Keyword(s):  
Induction Period ◽  
Ethyl Ether ◽  
Reaction Order ◽  
Propagation Rate ◽  
Reaction Scheme ◽  
Polymerization Kinetics ◽  
Polymerization Rate ◽  
Constant Concentration ◽  
Initial Concentration ◽  
Kinetics Of

The effect of small additions of 1-octene, butyl ethyl ether and triethylamine on the polymerization kinetics of isoprene (2-methyl-1,3-butadiene) in benzene initiated with butyllithium was investigated by employing the GLC analysis. The addition of 1-octane was reflected only in a shorter induction period of the reaction; the effect on the propagation rate was insignificant. With the increasing amount of butyl ethyl ether, the polymerization rate increases linearly, while the reaction order with respect to the concentration of triethylamine is variable and increases from 0.33 to 0.66 with the increasing concentration of the initiator. For a constant concentration of triethylamine, the reaction order with respect to the initial concentration of the initiator was found to vary considerably, reaching even negative values. A reaction scheme was suggested, taking into account the competition between two different solvates of alkyllithium.

The Reactivity of Different Active Forms of Sodium Carbonate with Respect to Sulfur Dioxide

1992 ◽  
Vol 57 (11) ◽  
pp. 2302-2308
Author(s):  
Karel Mocek ◽  
Erich Lippert ◽  
Emerich Erdös
Keyword(s):  
Thermal Decomposition ◽  
Liquid Phase ◽  
Sulfur Dioxide ◽  
Specific Surface ◽  
Surface Area ◽  
Sodium Carbonate ◽  
Room Temperature ◽  
Active Form ◽  
The Other ◽  
Kinetics Of

The kinetics of the reaction of solid sodium carbonate with sulfur dioxide depends on the microstructure of the solid, which in turn is affected by the way and conditions of its preparation. The active form, analogous to that obtained by thermal decomposition of NaHCO3, emerges from the dehydration of Na2CO3 . 10 H2O in a vacuum or its weathering in air at room temperature. The two active forms are porous and have approximately the same specific surface area. Partial hydration of the active Na2CO3 in air at room temperature followed by thermal dehydration does not bring about a significant decrease in reactivity. On the other hand, if the preparation of anhydrous Na2CO3 involves, partly or completely, the liquid phase, the reactivity of the product is substantially lower.

Studies on Thermal Decomposition Kinetics of Polyvinyl Nitrate

1995 ◽  
Vol 20 (2) ◽  
pp. 91-95 ◽  
Author(s):  
S. C. Mishra ◽  
Jyotsna Pant ◽  
G. C. Pant ◽  
P. K. Dutta ◽  
U. C. Durgapal
Keyword(s):  
Thermal Decomposition ◽  
Decomposition Kinetics ◽  
Thermal Decomposition Kinetics ◽  
Polyvinyl Nitrate ◽  
Kinetics Of
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