Statistical Thermodynamics of Polymer Solutions. I. Theory of the Second Virial Coefficient for a Homogeneous Solute

1958 ◽  
Vol 29 (3) ◽  
pp. 493-503 ◽  
Author(s):  
Edward F. Casassa ◽  
Hershel Markovitz
Keyword(s):  
Virial Coefficient ◽  
Polymer Solutions ◽  
Second Virial Coefficient ◽  
Statistical Thermodynamics

On the Osmotic Second Virial Coefficient of Polymer Solutions

1976 ◽  
Vol 9 (2) ◽  
pp. 303-307 ◽  
Author(s):  
M. Janssens ◽  
A. Bellemans
Keyword(s):  
Virial Coefficient ◽  
Polymer Solutions ◽  
Second Virial Coefficient

Statistical Thermodynamics of Two-Dimensional Fluids of Solid Nanoparticles

2003 ◽  
Vol 782 ◽  
Author(s):  
Liudmila A. Pozhar ◽  
John Maguire
Keyword(s):  
Isothermal Compressibility ◽  
Virial Coefficient ◽  
Second Virial Coefficient ◽  
Statistical Thermodynamics ◽  
Two Dimensional ◽  
Nano Composite ◽  
Rigid Particles ◽  
Polygonal Shape ◽  
Simulations And Modeling ◽  
Analytical Expressions

ABSTRACTThe second virial coefficient-based statistical thermodynamics of a diluted fluid of rigid particles of regular polygonal shape is discussed. Analytical expressions for the second virial coefficient, surface tension, isothermal compressibility and isothermal speed of sound are derived in this approximation. The obtained results provide analytical guidelines for numerical simulations and modeling studies of two-dimensional (2D) particulate fluids (thin films) widely used in processing of model (nano)composite materials and other technological processes.

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