Statistical Thermodynamics of Polymer Solutions. II. Excluded Volume Effect and Second Virial Coefficient

1959 ◽  
Vol 31 (3) ◽  
pp. 800-808 ◽  
Author(s):  
Edward F. Casassa
Keyword(s):  
Virial Coefficient ◽  
Polymer Solutions ◽  
Second Virial Coefficient ◽  
Statistical Thermodynamics ◽  
Volume Effect ◽  
Excluded Volume ◽  
Excluded Volume Effect

HEATS OF DILUTION OF POLYISOBUTYLENE SOLUTIONS

1962 ◽  
Vol 40 (4) ◽  
pp. 734-738 ◽  
Author(s):  
M. Senez ◽  
H. Daoust
Keyword(s):  
Virial Coefficient ◽  
Second Virial Coefficient ◽  
Volume Effect ◽  
Excluded Volume ◽  
Dilution Technique ◽  
Molecular Weights ◽  
Calvet Microcalorimeter ◽  
Heats Of Dilution ◽  
Excluded Volume Effect ◽  
Benzene Toluene

The measurements of heats of dilution of polyisobutylene solutions in benzene, toluene, and chlorobenzene have been carried out with a Tian–Calvet microcalorimeter at 25 °C. The dilution technique previously described has been improved and the extrapolated enthalpy parameter κ1* for each system has been corrected for the excluded volume effect using the Krigbaum–Carpenter–Kaneko–Roig formulation for the second virial coefficient A2. No detectable variation in κ1* was found for high molecular weights (≥ 43,000); but a definite increase in κ1* was found for very low molecular weights.

scholarly journals Excluded volume effect enhances the homology pairing of model chromosomes

2016 ◽  
Vol 7 (2) ◽  
pp. 66-75 ◽  
Author(s):  
Kazunori Takamiya ◽  
Keisuke Yamamoto ◽  
Shuhei Isami ◽  
Hiraku Nishimori ◽  
Akinori Awazu
Keyword(s):  
Volume Effect ◽  
Excluded Volume ◽  
Excluded Volume Effect

Excluded volume effect for the nuclear matter equation of state

1991 ◽  
Vol 51 (3) ◽  
pp. 485-489 ◽  
Author(s):  
D. H. Rischke ◽  
M. I. Gorenstein ◽  
H. St�cker ◽  
W. Greiner
Keyword(s):  
Equation Of State ◽  
Nuclear Matter ◽  
Volume Effect ◽  
Excluded Volume ◽  
Excluded Volume Effect
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