Fast Vacuum‐uv Light Source for Gas Phase Flash Photolysis

1967 ◽  
Vol 38 (12) ◽  
pp. 1728-1730 ◽  
Author(s):  
K. H. Welge ◽  
J. Wanner ◽  
F. Stuhl ◽  
A. Heindrichs
2012 ◽  
Vol 32 ◽  
pp. 477-481 ◽  
Author(s):  
Bu Ren’an ◽  
Song Mingdong ◽  
Wang Zhongrui ◽  
Jin Jing ◽  
Hu Wenbo ◽  
...  
Keyword(s):  
Uv Light ◽  

1983 ◽  
Vol 61 (5) ◽  
pp. 861-865 ◽  
Author(s):  
Jean-Pierre Martin ◽  
George Paraskevopoulos

A kinetic study of the reactions of OH radicals with a series of fluoroethanes in the gas phase is presented. OH radicals were generated by flash photolysis of H2O vapor in the vacuum uv (λ > 165 nm) and were monitored in absorption by time-resolved attenuation of resonance radiation at 308.15 nm [OH(A2Σ+ → X2Π)]. The following absolute rate constants (in units of 109 cm3mol−1 s−1 at the 95% confidence limit) were determined at [Formula: see text][Formula: see text][Formula: see text][Formula: see text][Formula: see text]From a linear correlation of the present and previously published rate constants with bond dissociation energies, the following quantities (in kcal mol−1 at 298 K) were estimated to be: D(CH3CHF—H) = 96.3 ± 1.5, D(CH2FCHF—H = 98.8 ± 1.0, D(CF3CHF—H) = 103.5 ± 1.0, D(CHF2CF2—H) = 103.0 ± 1.5, and [Formula: see text][Formula: see text]


2015 ◽  
Vol 135 (9) ◽  
pp. 1049-1054
Author(s):  
Norio Ichikawa ◽  
Kohei Ikeda ◽  
Yoshinori Honda ◽  
Hiroyuki Taketomi ◽  
Koji Kawai ◽  
...  

2004 ◽  
Vol 32 (5) ◽  
pp. 2093-2098 ◽  
Author(s):  
B.G. Salamov ◽  
Y. OztekinCiftci ◽  
K. Colakoglu
Keyword(s):  

2021 ◽  
Vol 903 ◽  
pp. 11-16
Author(s):  
M.A. Manjunath ◽  
K. Naveen ◽  
Prakash Vinod ◽  
N. Balashanmugam ◽  
M.R. Shankar

Polymethyl methacrylate (PMMA) is one among few known photo-polymeric resin useful in lithography for fabricating structures having better mechanical properties to meet the requirement in electronics and biomedical applications. This study explores the effect of Photo Initiator (PI) concentration and also curing time on strength and hardness of Polymethyl methacrylate (PMMA) obtained by UV photopolymerization of Methyl methacrylate (MMA) monomer. The UV LED light source operating at the wavelength of 364 nm is used with Benzoin Ethyl Ether (BEE) as photo initiator. The curing of PMMA resin is supported with peltier cooling device placed at the bottom of the UV light source. The characterisation study of UV photo cured PMMA is analysed through nano indenter (Agilent Technologies-G200). The current work investigates the influence of PI concentration and curing time in achieving maximum mechanical properties for UV photopolymerized PMMA.


1976 ◽  
Vol 15 (12) ◽  
pp. 2968
Author(s):  
S. F. Somerstein
Keyword(s):  

1997 ◽  
Vol 35 (4) ◽  
pp. 41-48 ◽  
Author(s):  
T.M. Hashem ◽  
M. Zirlewagen ◽  
A. M. Braun

A more efficient use of vacuum ultraviolet (VUV) radiation produced by an immersed Xe-excimer light source (172 nm) was investigated for the oxidative degradation of organic pollutants in aqueous systems. All emitted VUV radiation from one light source was used in two simultaneous but separate photochemical reactions: (1) photochemical generation of ozone by irradiating oxygen in the gas phase and (2) photolysis of the aqueous reaction system. The gas stream containing the generated ozone is sparged into the reaction system, thus enhancing the oxidative degradation of organic pollutants. The photochemically generated ozone in the gas phase was quantitatively analyzed, and the kinetics of the degradation of 4-chlorophenol (4-CP) and of the dissolved organic carbon (DOC) were determined under different experimental conditions. The results show that the rates of degradation of the substrate and of the DOC decrease in the order of the applied processes, VUV/O3 > O3 > VUV.


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