Measurement of Pole Figures and Orientation Functions for Polyethylene Films Prepared by Unidirectional and Oriented Crystallization

1966 ◽  
Vol 37 (11) ◽  
pp. 3990-4002 ◽  
Author(s):  
C. R. Desper ◽  
R. S. Stein
Keyword(s):  
Polyethylene Films ◽  
Oriented Crystallization ◽  
Pole Figures

The analysis of “Gels” in polymer films

1989 ◽  
Vol 47 ◽  
pp. 362-363
Author(s):  
G. M. Brown ◽  
D. F. Brown ◽  
J. H. Butler
Keyword(s):  
Molecular Weight ◽  
Film Industry ◽  
Local Stress ◽  
Melt Index ◽  
Polyethylene Films ◽  
Crosslinked Polymer ◽  
Polymeric Gels ◽  
Mineral Particles ◽  
Polymeric Species ◽  
Special Concern

The term “gel”, in the jargon of the plastics film industry, may refer to any inclusion that produces a visible artifact in a polymeric film. Although they can occur in any plastic product, gels are a principle concern in films where they detract from the cosmetic appearance of the product and may compromise its mechanical strength by acting as local stress concentrators. Many film gels are small spheres or ellipsoids less than one millimeter in diameter whereas other gels are fusiform-shaped and may reach several centimeters in length. The actual composition of gel inclusions may vary from miscellaneous inorganics (i.e. glass and mineral particles) and processing additives to heavily oxidized, charred or crosslinked polymer. The most commonly observed gels contain polymer differing from the bulk of the sample in its melt viscosity, density or molecular weight.Polymeric gels are a special concern in polyethylene films. Over the years and with the examination of a variety of these samples three predominant polymeric species have been observed: density gels which have different crystallinity than the film; melt-index gels in which the molecular weight is different than the film and crosslinked gels which are comprised of crosslinked polyethylene.

Use of generalised pole figures in the X-ray study of textured metal materials

2007 ◽  
Vol 2007 (suppl_26) ◽  
pp. 327-332
Author(s):  
Yu. Perlovich ◽  
M. Isaenkova ◽  
V. Fesenko
Keyword(s):  
X Ray ◽  
Pole Figures ◽  
Metal Materials

MISORIENTATION DISTRIBUTION FUNCTION FOR CUBIC CRYSTALS

2019 ◽  
Vol 85 (5) ◽  
pp. 28-32
Author(s):  
A. S. Kolyanova ◽  
Y. N. Yaltsev
Keyword(s):  
Distribution Function ◽  
Grain Boundaries ◽  
Orientation Distribution ◽  
Recrystallization Annealing ◽  
Misorientation Distribution ◽  
Cubic Crystals ◽  
Special Boundaries ◽  
Pole Figures ◽  
Two Samples ◽  
Euler Space

A calculation method for obtaining the misorientation distribution function (MDF) for cubic crystals which can be used to estimate the presence or absence of special boundaries in the materials is presented. The calculation was carried out for two samples of Al-Mg-Si alloy subjected to various mechanical and thermal treatments: the first sample is subjected to rolling; the second sample is subjected to recrystallization annealing. MDF is calculated for each sample; the results are presented in the Euler space and in the angle-axis space. The novelty of the method consists in the possibility of gaining data on the grain boundaries from X-ray texture analysis without using electron microscopy. A calculation involving only mathematical operations on matrices was performed on the basis of the orientation distribution function restored from incomplete pole figures. It is shown that no special boundaries are observed in the deformed sample, whereas in the recrystallized alloy, special boundaries are detected at Ʃ = 23, 13, and 17. The shortcoming of the proposed method can be attributed to the lack of accurate data on grain boundaries, since all possible orientation in the polycrystal should be taken into account in MDF calculation.

scholarly journals Low-Density Polyethylene Films Carrying ferula asafoetida Extract for Active Food Packaging: Thermal, Mechanical, Optical, Barrier, and Antifungal Properties

2020 ◽  
Vol 2020 ◽  
pp. 1-15
Author(s):  
Razieh Niazmand ◽  
Bibi Marzieh Razavizadeh ◽  
Farzaneh Sabbagh
Keyword(s):  
Polymer Matrix ◽  
Food Packaging ◽  
Barrier Properties ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Optical Barrier ◽  
Leaf Extracts ◽  
Polyethylene Films ◽  
Active Food Packaging ◽  
Ferula Asafoetida

The physical, thermal, mechanical, optical, microstructural, and barrier properties of low-density polyethylene films (LDPE) containing ferula asafoetida leaf and gum extracts were investigated. Results showed a reduction in elasticity and tensile strength with increasing extract concentration in the polymer matrix. The melting temperature and enthalpy increased with increasing concentration of extracts. The films containing extracts had lower L∗ and a∗ and higher b∗ indices. The films containing leaf extract had more barrier potential to UV than the gum extracts. The oxygen permeability in films containing 5% of leaf and gum extracts increased by 2.3 and 2.1 times, respectively. The morphology of the active films was similar to bubble swollen islands, which was more pronounced at higher concentrations of gum and leaf extracts. FTIR results confirmed some chemical interactions of ferula extracts with the polymer matrix. At the end of day 14th, the growth rate of Aspergillus niger and Saccharomyces cerevisea in the presence of the PE-Gum-5 reduced more than PE-Leaf-5 (3.7 and 2.4 logarithmic cycles, respectively) compared to the first day. Our findings showed that active LDPE films have desire thermo-mechanical and barrier properties for food packaging.

scholarly journals Study on a New Forming Method—Thread Rolling by Crystal Plasticity Finite Element Simulation

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 503
Author(s):  
Yuheng Zhang ◽  
Zhiqing Hu ◽  
Liming Guo
Keyword(s):  
Finite Element ◽  
Crystal Plasticity ◽  
Strain Curve ◽  
Forming Process ◽  
Crystal Plasticity Finite Element ◽  
Pole Figures ◽  
Grain Orientations ◽  
Thread Rolling ◽  
Polycrystalline Model ◽  
High Consistency

In order to study a new thread rolling forming process from a microscopic perspective, a polycrystalline model was established, based on the crystal plasticity finite element method (CPFEM) and Voronoi polyhedron theory. The fluidity of metals was studied to explain the reason for the concave center. The simulation results show that the strain curve of the representative element can more truly reflect the deformation behavior of the material. The grain orientations after deformation are distributed near the initial orientation. The evolution of each slip system is determined by the initial grain orientations and grain locations. The pole figures obtained from the experiment show high consistency with the pole figures obtained by simulation, which verifies the accuracy of the texture prediction by CPFEM. The experimental results show that thread rolling is more uniform in deformation than ordinary rolling.

scholarly journals Symmetry Breakdown Related Fracture in 42CrMo4 Steel

Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 344
Author(s):  
Jian Feng ◽  
Stefan Barth ◽  
Marc Wettlaufer
Keyword(s):  
Orientation Distribution ◽  
High Symmetry ◽  
Symmetry Breakdown ◽  
Pole Figures ◽  
Crystallographic Symmetry ◽  
42Crmo4 Steel ◽  
Austenite Grains ◽  
Ebsd Technique ◽  
Complete Transformation ◽  
Start Temperature

Austenite grains that underwent the f.c.c. to b.c.c. (or b.c.t.) transformation are typically composed of 24 Kurdjumov–Sachs variants that can be categorized by three axes of Bain transformations; thus, a complete transformation generally displays 3-fold symmetry in (001) pole figures. In the present work, crystallographic symmetry in 42CrMo4 steel austempered below martensite start temperature was investigated with the help of the orientation distribution function (ODF) analysis based on the FEG-SEM/EBSD technique. It is shown that, upon phase transformations, the specimens contained 6-fold symmetry in all (001), (011), and (111) pole figures of an ODF. The ODF analysis, verified by theoretical modeling, showed that under plane-strain conditions cracks prefer to propagate through areas strongly offset by the high symmetry. The origin of high symmetry was investigated, and the mechanism of the symmetry breakdown was explained.

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