Application of the Cell Method to the Statistical Thermodynamics of Solutions

1952 ◽  
Vol 20 (1) ◽  
pp. 49-57 ◽  
Author(s):  
I. Prigogine ◽  
V. Mathot
Keyword(s):  
Statistical Thermodynamics ◽  
Cell Method ◽  
Thermodynamics Of Solutions

The statistical thermodynamics of solutions of non-spherical molecules. I. The thermodynamic functions

1955 ◽  
Vol 229 (1177) ◽  
pp. 271-280 ◽  
Keyword(s):  
Carbon Tetrachloride ◽  
Equation Of State ◽  
Thermodynamic Functions ◽  
Statistical Thermodynamics ◽  
Intermolecular Forces ◽  
Pure Component ◽  
Experimental Results ◽  
Thermodynamics Of Solutions ◽  
Theory And Experiment

The perturbation treatment of the orientational forces between non-spherical molecules proposed by Cook & Rowlinson (1953) is extended to mixtures by using the theory of solutions put forward by Longuet-Higgins (1951). The thermodynamic functions and the equation of state of such mixtures are expressed in terms of the intermolecular forces and the properties of one pure component. Expressions are derived for the excess (or non-ideal) thermodynamic functions which are compared with the experimental results on the four solutions, benzene+ cyclohexane , benzene+carbon tetrachloride, benzene + ethylene dychloride, and cyclohexane + carbon tetrachloride. The agreement between theory and experiment is improved by taking account of the orientational forces.

Statistical thermodynamics of solutions of polymers in mixed solvents

Polymer ◽  
1971 ◽  
Vol 12 (5) ◽  
pp. 290-308 ◽  
Author(s):  
Misazo Yamamoto ◽  
James L. White ◽  
Donald L. MacLean
Keyword(s):  
Mixed Solvents ◽  
Statistical Thermodynamics ◽  
Thermodynamics Of Solutions

Statistical Thermodynamics of Solutions

1956 ◽  
Vol 24 (3) ◽  
pp. 518-527 ◽  
Author(s):  
I. Prigogine ◽  
A. Bellemans ◽  
A. Englert‐Chwoles
Keyword(s):  
Statistical Thermodynamics ◽  
Thermodynamics Of Solutions
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