Application of the Cell Model to the Statistical Thermodynamics of Solutions. Volume Change of Mixing in Solutions of Molecules Slightly Different in Size

1953 ◽  
Vol 21 (3) ◽  
pp. 561-562 ◽  
Author(s):  
I. Prigogine ◽  
A. Bellemans
Keyword(s):  
Volume Change ◽  
Cell Model ◽  
Statistical Thermodynamics ◽  
Thermodynamics Of Solutions

The statistical thermodynamics of solutions of non-spherical molecules. I. The thermodynamic functions

1955 ◽  
Vol 229 (1177) ◽  
pp. 271-280 ◽  
Keyword(s):  
Carbon Tetrachloride ◽  
Equation Of State ◽  
Thermodynamic Functions ◽  
Statistical Thermodynamics ◽  
Intermolecular Forces ◽  
Pure Component ◽  
Experimental Results ◽  
Thermodynamics Of Solutions ◽  
Theory And Experiment

The perturbation treatment of the orientational forces between non-spherical molecules proposed by Cook & Rowlinson (1953) is extended to mixtures by using the theory of solutions put forward by Longuet-Higgins (1951). The thermodynamic functions and the equation of state of such mixtures are expressed in terms of the intermolecular forces and the properties of one pure component. Expressions are derived for the excess (or non-ideal) thermodynamic functions which are compared with the experimental results on the four solutions, benzene+ cyclohexane , benzene+carbon tetrachloride, benzene + ethylene dychloride, and cyclohexane + carbon tetrachloride. The agreement between theory and experiment is improved by taking account of the orientational forces.

Thermodynamics of solutions--Volume change on mixing for four systems

1967 ◽  
Vol 12 (2) ◽  
pp. 193-196 ◽  
Author(s):  
H. William Prengle ◽  
E. G. Felton ◽  
Martin A. Pike
Keyword(s):  
Volume Change ◽  
Thermodynamics Of Solutions

Statistical thermodynamics of solutions of polymers in mixed solvents

Polymer ◽  
1971 ◽  
Vol 12 (5) ◽  
pp. 290-308 ◽  
Author(s):  
Misazo Yamamoto ◽  
James L. White ◽  
Donald L. MacLean
Keyword(s):  
Mixed Solvents ◽  
Statistical Thermodynamics ◽  
Thermodynamics Of Solutions
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